Nickel-Catalyzed 1,1-Aminoborylation of Unactivated Terminal Alkenes

被引：0

作者：

Talavera, Laura ^{[1
,2
]}

Freund, Robert R. A. ^{[1
]}

Zhang, Huihui ^{[1
]}

Wakeling, Matthew ^{[1
]}

Jensen, Mara ^{[1
]}

Martin, Ruben ^{[1
,3
]}

机构：

[1] Barcelona Inst Sci & Technol, Inst Chem Res Catalonia ICIQ, Tarragona 43007, Spain

[2] Univ Rovira & Virgili, Dept Quim Analit & Quim Organ, Tarragona 43007, Spain

[3] ICREA, Barcelona 08010, Spain

来源：

ACS CATALYSIS | 2023年

基金：

欧洲研究理事会;

关键词：

nickel; unactivated alkenes; aminoborylation; chain walking; site selectivity;

D O I：

暂无

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Herein, we disclose a Ni-catalyzed 1,1-difunctionalization of unactivated terminal alkenes that enables the incorporation of two different heteroatom motifs across an olefin backbone, thus streamlining the access to alpha-aminoboronic acid derivatives from simple precursors. The method is characterized by its simplicity and generality across a wide number of coupling counterparts.

引用

页码：5538 / 5543

页数：6

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