Influence of Cu on modifying the beta phase and enhancing the mechanical properties of recycled Al-Si-Fe cast alloys

被引:29
作者
Basak, C. B. [1 ]
Babu, N. Hari [1 ]
机构
[1] Brunel Univ London, BCAST, Kingston Lane, Uxbridge UB8 3PH, Middx, England
来源
SCIENTIFIC REPORTS | 2017年 / 7卷
基金
英国工程与自然科学研究理事会;
关键词
PART I; INTERMETALLIC PHASES; IRON-INTERMETALLICS; MICROSTRUCTURE; PERFORMANCE; POROSITY; COPPER;
D O I
10.1038/s41598-017-05937-2
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
High iron impurity affects the castability and the tensile properties of the recycled Al- Si alloys due to the presence of the Fe containing intermetallic beta- Al9Fe2Si2 phase. To date only Mn addition is known to transform the beta-Al9Fe2Si2 phase in the Al-Si-Fe system. However, for the first time, as reported here, it is shown that beta- phase transforms to the omega-Al7Cu2Fe phase in the presence of Cu, after solutionization at 793 K. The omega-phase decomposes below 673 K resulting into the formation of theta-Al2Cu phase. However, the present thermodynamic description of the Al-Si-Fe-Cu system needs finer tuning to accurately predict the stability of the omega-phase in these alloys. In the present study, an attempt was made to enhance the strength of Al-6wt% Si-2wt% Fe model recycled cast alloy with different amount of Cu addition. Microstructural and XRD analysis were carried out in detail to show the influence of Cu and the stability range of the omega-phase. Tensile properties and micro-hardness values are also reported for both as-cast and solutionized alloys with different amount of Cu without and with ageing treatment at 473 K. The increase in strength due to addition of Cu, in Fe-rich Al-Si alloys is promising from the alloy recyclability point of view.
引用
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页数:10
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共 38 条
  • [11] Improving aluminum recycling: A survey of sorting and impurity removal technologies
    Gaustad, Gabrielle
    Olivetti, Elsa
    Kirchain, Randolph
    [J]. RESOURCES CONSERVATION AND RECYCLING, 2012, 58 : 79 - 87
  • [12] Assuring the continued recycling of light metals in end-of-life vehicles: A global perspective
    Gesing, A
    [J]. JOM, 2004, 56 (08) : 18 - 27
  • [13] Evolution of Fe based intermetallic phases in Al-Si hypoeutectic casting alloys: Influence of the Si and Fe concentrations, and solidification rate
    Gorny, Anton
    Manickaraj, Jeyakumar
    Cai, Zhonghou
    Shankar, Sumanth
    [J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2013, 577 : 103 - 124
  • [14] Green J. A. S., 2007, ALUMINUM RECYCLING P, P15
  • [15] Iwahori H., 1988, IMONO, V60, P590
  • [16] Effect of iron on the microstructure and mechanical property of Al-Mg-Si-Mn and Al-Mg-Si diecast alloys
    Ji, Shouxun
    Yang, Wenchao
    Gao, Feng
    Watson, Douglas
    Fan, Zhongyun
    [J]. MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2013, 564 : 130 - 139
  • [17] Kamavaram V., 2003, J MIN METALL B, V39, P43, DOI DOI 10.2298/JMMB0302043K
  • [18] Larson A. C., 2000, REPORT LAUR 86 748
  • [19] Parameters controlling the performance of AA319-type alloys Part I. Tensile properties
    Li, Z
    Samuel, AM
    Samuel, FH
    Ravindran, C
    Valtierra, S
    Doty, HW
    [J]. MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2004, 367 (1-2): : 96 - 110
  • [20] A study of tensile properties in Al-Si-Cu and Al-Si-Mg alloys:: Effect of β-iron intermetallics and porosity
    Ma, Z.
    Samuel, A. M.
    Samuel, F. H.
    Doty, H. W.
    Valtierra, S.
    [J]. MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2008, 490 (1-2): : 36 - 51