Metal-center exchange of tetrahedral cages: single crystal to single crystal and spin-crossover properties

被引：27
|
作者：
Zhang, Feng-Li [1 ]
Chen, Jia-Qian [1 ]
Qin, Long-Fang [1 ]
Tian, Lei [1 ]
Li, Zaijun [1 ]
Ren, Xuehong [2 ]
Gu, Zhi-Guo [1 ]
机构：
[1] Jiangnan Univ, Sch Chem & Mat Engn, Key Lab Food Colloids & Biotechnol, Minist Educ, Wuxi 214122, Peoples R China
[2] Jiangnan Univ, Coll Text & Clothing, Key Lab Ecotext, Minist Educ, Wuxi 214122, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2016年 / 52卷 / 26期
基金：
中国国家自然科学基金;
关键词：
ORGANIC FRAMEWORKS; CATION-EXCHANGE; COORDINATION POLYMERS; CHARGE-TRANSFER; TRANSITION; COMPLEXES; TRANSFORMATION; LIGAND; SPECTROSCOPY; METATHESIS;
D O I：
10.1039/c6cc00711b
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An effective single crystal to single crystal transformation from a tetrahedral Ni cage to an FeNi cage was demonstrated. The iron(II) centers of the FeNi cage can be induced to display spin crossover behaviors with an increasing amount of Fe(II) ions. The SCSC metal-center exchange provides a powerful approach to modify solid magnetic properties.
引用
收藏
页码：4796 / 4799
页数：4
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