Synthesis and photoluminescence properties of a red-emitting phosphor, K2SiF6:Mn4+, for use in three-band white LED applications

被引:26
作者
Yeo, Byul-Ee [1 ]
Cho, Young-Sik [1 ]
Huh, Young-Duk [1 ]
机构
[1] Dankook Univ, Dept Chem, Gyeonggi Do 448701, South Korea
关键词
Red-emitting phosphors; K2SiF6:Mn4+; Photoluminescence; LUMINESCENCE PROPERTIES; OPTICAL-PROPERTIES; NITRIDE; DIODES; TEMPERATURE; CONVERSION;
D O I
10.1016/j.optmat.2015.11.014
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
K2SiF6:Mn4+ phosphors were prepared by redox precipitation at room temperature from mixed aqueous solutions of SiO2, HF, KMnO4, and H2O2. The optimal conditions required to obtain the brightest red emission spectra of the K2SiF6:Mn4+ phosphors were examined. The K2SiF6:Mn4+ phosphors emitted deep red light with three strong peaks at 615, 630, and 650 nm under 465 nm excitation, the emission wavelength of a commercial blue LED. K2SiF6:Mn4+ and SrGa2S4:Eu2+ phosphors were used to produce the red and green emission bands under excitation from a commercial blue LED, respectively. The photoluminescence properties of the three-band white LEDs fabricated by coating K2SiF6:Mn4+ and SrGa2S4:Eu2+ phosphors onto the commercial blue LED chip were investigated. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码:50 / 55
页数:6
相关论文
共 33 条
[1]   On the optical properties of the Mn4+ ion in solids [J].
Brik, M. G. ;
Srivastava, A. M. .
JOURNAL OF LUMINESCENCE, 2013, 133 :69-72
[2]  
Christie K. O., 2013, EFFICIENT PREPARATIO, P1
[3]   Efficient red phosphors Na5Ln(MoO4)4 : Eu3+ (Ln = La, Gd and Y) for white LEDs [J].
Guo, Chongfeng ;
Gao, Fei ;
Xu, Yan ;
Liang, Lifang ;
Shi, Frank G. ;
Yan, Bohan .
JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2009, 42 (09)
[4]   Characterization and properties of green-emitting β-SiAlON:Eu2+ powder phosphors for white light-emitting diodes -: art. no. 211905 [J].
Hirosaki, N ;
Xie, RJ ;
Kimoto, K ;
Sekiguchi, T ;
Yamamoto, Y ;
Suehiro, T ;
Mitomo, M .
APPLIED PHYSICS LETTERS, 2005, 86 (21) :1-3
[5]   Optical properties of three-band white light emitting diodes [J].
Huh, YD ;
Shim, JH ;
Kim, Y ;
Do, YR .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2003, 150 (02) :H57-H60
[6]  
Huh YD, 2002, B KOREAN CHEM SOC, V23, P1435
[7]   Red and Deep Red Emissions from Cubic K2SiF6:Mn4+ and Hexagonal K2MnF6 Synthesized in HF/KMnO4/KHF2/Si Solutions [J].
Kasa, Ryota ;
Adachi, Sadao .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2012, 159 (04) :J89-J95
[8]  
Kojima T, 1999, CRC LAS OPT SCI TECH, P623
[9]   Photoluminescence of CaAlSiN3:Eu2+-based fine red-emitting phosphors synthesized by carbothermal reduction and nitridation method [J].
Li, Shuxing ;
Peng, Xia ;
Liu, Xuejian ;
Huang, Zhengren .
OPTICAL MATERIALS, 2014, 38 :242-247
[10]   Shape-controlled synthesis of phosphor K2SiF6: Mn4+ nanorods and their luminescence properties [J].
Li, Xiaoqing ;
Su, Xiangming ;
Liu, Ping ;
Liu, Jie ;
Yao, Zhiling ;
Chen, Jiajun ;
Yao, Hui ;
Yu, Xibin ;
Zhan, Ming .
CRYSTENGCOMM, 2015, 17 (04) :930-936