The enormous apparent gas-phase acidity of cubylamine

被引：6

作者：

Abboud, JLM

Alkorta, I

Burk, P

Dávalos, JZ

Quintanilla, E

Della, EW

Koppel, IA

Koppel, I

机构：

[1] CSIC, Inst Quim Fis Rocasolano, E-28006 Madrid, Spain

[2] CSIC, Inst Quim Med, E-28006 Madrid, Spain

[3] Univ Tartu, Inst Phys Chem, EE-51014 Tartu, Estonia

[4] Flinders Univ S Australia, Dept Chem, Bedford Pk, SA 5042, Australia

来源：

CHEMICAL PHYSICS LETTERS | 2004年 / 398卷 / 4-6期

关键词：

D O I：

10.1016/j.cplett.2004.09.127

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The high acidity of cubylamine (1NH(2)) seems to originate in the release of strain energy attending the breaking of some C-C bonds in 1NH(-). This process is greatly facilitated by the strong stereoelectronic interactions in 1NH-. The anionic species thus formed are less strained, and their corresponding conjugate acids seem unable to 'borrow strength' from the residual strain, at least within the time-scale of the FT ICR experiments. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：560 / 563

页数：4

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