The influence of the spacer Z on N-phosphorylated bis-thioureas and 2,5-dithiobiurea Z[C(S)NHP(O)(OiPr)2]2 (Z = -NHCH2CH2NH-, -NHC6H4-2-NH-, -NHNH-) crystal design

被引：13

作者：

Safin, Damir A. ^{[1
]}

Babashkina, Maria G. ^{[1
]}

Bolte, Michael ^{[2
]}

Klein, Axel ^{[1
]}

机构：

[1] Univ Cologne, Inst Anorgan Chem, D-50939 Cologne, Germany

[2] Goethe Univ Frankfurt, Inst Anorgan Chem, Frankfurt, Germany

来源：

POLYHEDRON | 2009年 / 28卷 / 08期

关键词：

N-phosphoryl bis-thiourea; Crystal structure; H-bond networks; NMR spectroscopy; Isomers; Thiosemicarbazide; BIPODAL THIOPHOSPHORYLATED THIOUREAS; METAL-CATIONS; CROWN-ETHERS; COMPLEXES;

D O I：

10.1016/j.poly.2009.02.044

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two new bifunctional N-phosphorylated thioureas and a 2,5-dithiobiurea of the common formula Z[C(S)NHP(O)(OiPr)(2)](2) [Z = -NHCH2CH2NH- (1), -NHC6H4-2-NH- (2), -NHNH- (3)] have been synthesized and characterized by NMR spectroscopy and single crystal X-ray diffraction. The structure of the compound 3 has been studied in CDCl3 and DMSO-d(6) solutions. (C) 2009 Elsevier Ltd. All rights reserved.

引用

页码：1403 / 1408

页数：6

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