A Significant Fluorescence Turn-On Probe for the Recognition of Al3+ and Its Application

被引：21

作者：

Xing, Zhiyong ^{[1
]}

Wang, Junli ^{[2
,3
]}

Huang, Junhui ^{[4
]}

Chen, Xiangfeng ^{[1
]}

Zong, Ziao ^{[1
]}

Fan, Chuanbin ^{[1
]}

Huang, Guimei ^{[1
]}

机构：

[1] Youjiang Med Univ Nationalities, Sch Lab Med, Baise 533000, Peoples R China

[2] Youjiang Med Univ Nationalities, Affiliated Hosp, Dept Reprod Med, Baise 533000, Peoples R China

[3] Youjiang Med Univ Nationalities, Environm Hlth Risk Assessment & Prevent Engn Ctr, Baise 533000, Peoples R China

[4] Inst Sci & Technol Informat, Baise 533000, Peoples R China

来源：

MOLECULES | 2022年 / 27卷 / 08期

基金：

中国国家自然科学基金;

关键词：

benzothiazole; fluorescence; Al3+; cell image; ABSORBENCY-RATIOMETRIC DETECTION; SCHIFF-BASE PROBE; CELL; ALUMINUM; SENSOR; WATER; NAPHTHALENE; ION; CHEMOSENSOR; SAMPLES;

D O I：

10.3390/molecules27082569

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

An easy prepared probe, BHMMP, was designed and synthesized, which displayed a significant fluorescence enhancement (over 38-fold) and obvious color change in the recognition of Al3+. The binding ratio of probe BHMMP to Al3+ was determined as 1:1, according to Job plot. The binding mechanism was fully clarified by the experiments, such as FT-IR spectrum, ESI-MS analysis, and H-1 NMR titration. A DFT study further confirmed the binding mode of BHMMP to Al3+. The limit of detection (LOD) for Al3+ was determined as low as 0.70 mu M, based on the fluorescence titration of BHMMP. Moreover, the results from real sample experiments, including real water samples, test papers, and cell images, well-demonstrated that BHMMP was capable of sensing Al3+ in environmental and biological systems.

引用

页数：15

共 69 条

[1] A cyanobiphenyl containing fluorescence "turn on" sensor for Al3+ ion in CH3CN-water [J].

Alici, Onder ;

Erdemir, Serkan .

SENSORS AND ACTUATORS B-CHEMICAL, 2015, 208 :159-163

[2] A novel turn on fluorescent probe for the determination of Al3+ and Zn2+ ions and its cells applications [J].

Aydin, Duygu .

TALANTA, 2020, 210

[3] Novel fluorescent Schiff bases as Al3+ sensors with high selectivity and sensitivity, and their bioimaging applications [J].

Berrones-Reyes, Jessica ;

Munoz-Flores, Blanca M. ;

Gomez-Trevino, Alberto ;

Treto-Suarez, Manuel A. ;

Paez-Hernandez, Dayan ;

Schott, Eduardo ;

Zarate, Ximena ;

Jimenez-Perez, Victor M. .

MATERIALS CHEMISTRY AND PHYSICS, 2019, 233 :89-101

[4] Simple salicylaldimine-functionalized dipodal bis Schiff base chromogenic and fluorogenic chemosensors for selective and sensitive detection of Al3+ and Cr3+ [J].

Chandra, Rukhmani ;

Manna, Amit Kumar ;

Sahu, Meman ;

Rout, Kalyani ;

Patra, Goutam K. .

INORGANICA CHIMICA ACTA, 2020, 499

[5] Distribution and phytotoxicity of soil labile aluminum fractions and aluminum species in soil water extracts and their effects on tall fescue [J].

Chen, Fangman ;

Ai, Honglian ;

Wei, Mengting ;

Qin, Chunliu ;

Feng, Yang ;

Ran, Shangming ;

Wei, Zhihui ;

Niu, Hong ;

Zhu, Qing ;

Zhu, Huihui ;

Chen, Liang ;

Sun, Jie ;

Hou, Haobo ;

Chen, Ke ;

Ye, Hengpeng .

ECOTOXICOLOGY AND ENVIRONMENTAL SAFETY, 2018, 163 :180-187

[6] AN ALL-ELECTRON NUMERICAL-METHOD FOR SOLVING THE LOCAL DENSITY FUNCTIONAL FOR POLYATOMIC-MOLECULES [J].

DELLEY, B .

JOURNAL OF CHEMICAL PHYSICS, 1990, 92 (01) :508-517

[7] A novel dual chemosensor for selective heavy metal ions Al3+, Cr3+ and its applicable cytotoxic activity, HepG2 living cell images and theoretical studies [J].

Dhineshkumar, Ezhumalai ;

Iyappan, Mathivanan ;

Anbuselvan, Chinnadurai .

JOURNAL OF MOLECULAR STRUCTURE, 2020, 1210

[8] A novel colorimetric-fluorescent probe for Al3+ and the resultant complex for F- and its applications in cell imaging [J].

Fu, Jiaxin ;

Yao, Kun ;

Chang, Yongxin ;

Li, Bai ;

Yang, Li ;

Xu, Kuoxi .

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2019, 222

[9] A highly sensitive and selective fluorescent probe for determination of Cu (II) and application in live cell imaging [J].

Fu, Ying ;

Pang, Xiao-Xiao ;

Wang, Zhi-Qiang ;

Chai, Qiong ;

Ye, Fei .

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2019, 208 :198-205

[10] Semiempirical GGA-type density functional constructed with a long-range dispersion correction [J].

Grimme, Stefan .

JOURNAL OF COMPUTATIONAL CHEMISTRY, 2006, 27 (15) :1787-1799

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