Zirconium phosphate chloride dimethyl sulfoxide, a reactive precursor of a large family of layered compounds

被引：19

作者：

Alberti, G

Bartocci, M

Santarelli, M

Vivani, R

机构：

[1] Department of Chemistry, University of Perugia, 06123 Perugia

来源：

INORGANIC CHEMISTRY | 1997年 / 36卷 / 17期

关键词：

D O I：

10.1021/ic9704389

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new layered compound of composition Zr-(PO4)Cl(CH3)(2)SO has been prepared by the substitution of bidentate anionic groups O2P(OH)(2)(-) of gamma-Zr(PO4)-O2P(OH)(2) . 2H(2)O with couples of monodentate Cl--dimmethyl sulfoxide ligands. The high reactivity of the new compound makes it a suitable precursor for the preparation of new layered derivatives of general formula Zr(PO4)LL', even containing functional groups of catalytic and electrochemical interest.

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页码：3574 / &

页数：3

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