Enhanced dielectric properties of PVDF-based composite film with BaTiO3@SrTiO3 nanoparticles

被引:7
作者
Zhao, Yang [1 ]
Zhang, Yongming [1 ]
He, Zemin [1 ]
Zhang, Huimin [1 ]
Wang, Haiyang [1 ]
Zhao, Yuzhen [1 ]
机构
[1] Xijing Univ, Sch Sci, Xian Key Lab Adv Photoelect Mat & Energy Convers, Xian 710123, Peoples R China
关键词
ENERGY-STORAGE DENSITY; CORE-SHELL PARTICLES; POLY(VINYLIDENE FLUORIDE); BATIO3; NANOPARTICLES; HIGH-PERMITTIVITY; POLYMER; NANOCOMPOSITES; CONSTANT; SRTIO3; FABRICATION;
D O I
10.1039/d2nj01425d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A new ceramic/polymer composite based on BaTiO3@SrTiO3 (BT@ST) nanoparticles and polyvinylidene fluoride (PVDF) has been prepared and it has been proved by XRD, SEM, and TEM techniques that the BaTiO3@SrTiO3 nanoparticles are dispersed in the polymer matrix. Further, the effects of the inorganic filler contents of BT@ST nanoparticles on the dielectric behavior and the thermal and physical properties of this composite are discussed. The results showed that the BT@ST/PVDF composite film exhibited a relatively high dielectric constant (epsilon), low loss tangent (tan delta), and good temperature stability. At the same time, the physical and thermal properties of the BT@ST/PVDF composite film remained stable, and this composite can be applied in future electronic device related fields.
引用
收藏
页码:10577 / 10583
页数:7
相关论文
共 47 条
[1]   SrTiO3-BaTiO3 nanocomposites with temperature independent permittivity and linear tunability fabricated using field-assisted sintering from chemically synthesized powders [J].
Airimioaei, M. ;
Buscaglia, M. T. ;
Tredici, I. ;
Anselmi-Tamburini, U. ;
Ciomaga, C. E. ;
Curecheriu, L. ;
Bencan, A. ;
Buscaglia, V. ;
Mitoseriu, L. .
JOURNAL OF MATERIALS CHEMISTRY C, 2017, 5 (35) :9028-9036
[2]   Synthesis and evaluation of PVDF-MgTiO3 polymer-ceramic composites for low-k dielectric applications [J].
Bharath, R. Sundararam ;
Chakraborthy, Tirthankar ;
Nhalil, Hariharan ;
Masin, B. ;
Ashok, K. ;
Sreemoolanadhan, H. ;
Oommen, Charlie ;
Elizabeth, Suja .
JOURNAL OF MATERIALS CHEMISTRY C, 2019, 7 (15) :4484-4496
[3]   Ultrafine core-shell BaTiO3@SiO2 structures for nanocomposite capacitors with high energy density [J].
Bi, Ke ;
Bi, Meihua ;
Hao, Yanan ;
Luo, Wei ;
Cai, Ziming ;
Wang, Xiaohui ;
Huang, Yunhui .
NANO ENERGY, 2018, 51 :513-523
[4]   Sonochemically produced ZnS-coated polystyrene core-shell particles for use in photonic crystals [J].
Breen, ML ;
Dinsmore, AD ;
Pink, RH ;
Qadri, SB ;
Ratna, BR .
LANGMUIR, 2001, 17 (03) :903-907
[5]   Coating of BaCO3 crystals with TiO2:: Versatile approach to the synthesis of BaTiO3 tetragonal nanoparticles [J].
Buscaglia, Maria Teresa ;
Buscaglia, Vincenzo ;
Alessio, Rocco .
CHEMISTRY OF MATERIALS, 2007, 19 (04) :711-718
[6]   A critical analysis of the α, β and γ phases in poly(vinylidene fluoride) using FTIR [J].
Cai, Xiaomei ;
Lei, Tingping ;
Sun, Daoheng ;
Lin, Liwei .
RSC ADVANCES, 2017, 7 (25) :15382-15389
[7]   Size and shape control of SrTiO3 particles grown by epitaxial self-assembly [J].
Calderone, VR ;
Testino, A ;
Buscaglia, MT ;
Bassoli, M ;
Bottino, C ;
Viviani, M ;
Buscaglia, V ;
Nanni, P .
CHEMISTRY OF MATERIALS, 2006, 18 (06) :1627-1633
[8]   Comparative Investigation of the Structure and Properties of Ferroelectric Poly(vinylidene fluoride) and Poly(vinylidene fluoride-trifluoroethylene) Thin Films Crystallized on Substrates [J].
Chen, Shuting ;
Yao, Kui ;
Tay, Francis Eng Hock ;
Chew, Lydia Li Shan .
JOURNAL OF APPLIED POLYMER SCIENCE, 2010, 116 (06) :3331-3337
[9]   Flexible Nanodielectric Materials with High Permittivity for Power Energy Storage [J].
Dang, Zhi-Min ;
Yuan, Jin-Kai ;
Yao, Sheng-Hong ;
Liao, Rui-Jin .
ADVANCED MATERIALS, 2013, 25 (44) :6334-6365
[10]   Fundamentals, processes and applications of high-permittivity polymer matrix composites [J].
Dang, Zhi-Min ;
Yuan, Jin-Kai ;
Zha, Jun-Wei ;
Zhou, Tao ;
Li, Sheng-Tao ;
Hu, Guo-Hua .
PROGRESS IN MATERIALS SCIENCE, 2012, 57 (04) :660-723