Ring contraction of 1,2-digermacyclohexa-3,5-dienes initiated by electron transfer reactions with TCNE

被引：6

作者：

Mochida, K ^{[1
]}

Shimizu, H ^{[1
]}

Nanjo, M ^{[1
]}

机构：

[1] Gakushuin Univ, Fac Sci, Dept Chem, Tokyo 1718588, Japan

来源：

CHEMISTRY LETTERS | 2000年 / 10期

关键词：

D O I：

10.1246/cl.2000.1226

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The thermal reaction of 1,2-digermacyclohexa-3,5-dienes with tetracyanoethylene (TCNE) gave 1-germacyclopenta-2,3-diene as a germylene extrusion compound through a charge-transfer complex. The 1-germacyclopenta-2,4-diene was trapped with TCNE to give 5,5,6,6-tetracyano-7-germanorbsmene.

引用

页码：1226 / 1227

页数：2

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