Ring contraction of 1,2-digermacyclohexa-3,5-dienes initiated by electron transfer reactions with TCNE

被引：6
|
作者：
Mochida, K [1 ]
Shimizu, H [1 ]
Nanjo, M [1 ]
机构：
[1] Gakushuin Univ, Fac Sci, Dept Chem, Tokyo 1718588, Japan
来源：
CHEMISTRY LETTERS | 2000年 / 10期
关键词：
D O I：
10.1246/cl.2000.1226
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The thermal reaction of 1,2-digermacyclohexa-3,5-dienes with tetracyanoethylene (TCNE) gave 1-germacyclopenta-2,3-diene as a germylene extrusion compound through a charge-transfer complex. The 1-germacyclopenta-2,4-diene was trapped with TCNE to give 5,5,6,6-tetracyano-7-germanorbsmene.
引用
收藏
页码：1226 / 1227
页数：2
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