From atactic to isotactic CO/p-methylstyrene copolymer by proper modification of Pd(II) catalysts bearing achiral α-diimines

被引：38
作者：
Binotti, B
Carfagna, C
Zuccaccia, C
Macchioni, A
机构：
[1] Univ Urbino, Ist Sci Chim, I-61029 Urbino, Italy
[2] Univ Perugia, Dipartimento Chim, I-06123 Perugia, Italy
来源：
CHEMICAL COMMUNICATIONS | 2005年 / 01期
关键词：
D O I：
10.1039/b411214h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Cationic Pd(II) complexes modified with achiral C-2v-symmetric alpha-diimine ligands allow preparation of atactic or isotactic stereoblock CO/p-methylstyrene copolymers; both catalyst activity and polyketone microstructure depend on the choice of alpha-diimine substituents and counterion.
引用
收藏
页码：92 / 94
页数：3
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