The NiCl2•2H2O-Li-Arene (cat.) combination as reducing system, part 6 -: Reduction of hydrazines, azo and azoxy compounds, and amine N-oxides with the NiCl2•2H2O-Li-DTBB (cat.) combination

被引：60

作者：

Alonso, F ^{[1
]}

Radivoy, G ^{[1
]}

Yus, M ^{[1
]}

机构：

[1] Univ Alicante, Fac Ciencias, Dept Quim Organ, E-03080 Alicante, Spain

来源：

TETRAHEDRON | 2000年 / 56卷 / 44期

关键词：

hydrazines; azo compounds; azoxy compounds; amine N-oxides; reduction;

D O I：

10.1016/S0040-4020(00)00797-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The NiCl2. 2H(2)O/Li/DTBB (10 mol%) combination allows the reduction of aromatic hydrazines 1 (to amines), azo compounds 2 (to primary amines), azoxy compounds 3 (to azo compounds or to primary amines, depending on the reaction conditions) or amine N-oxides 4 (to tertiary amines), under mild reaction conditions (THF, room temperature). (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：8673 / 8678

页数：6

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