Palladium-Catalyzed Transformations of Alkyl C-H Bonds

被引：1683

作者：

He, Jian ^{[1
]}

Wasa, Masayuki ^{[1
]}

Chan, Kelvin S. L. ^{[1
]}

Shao, Ojan ^{[1
]}

Yu, Jin-Quan ^{[1
]}

机构：

[1] Scripps Res Inst, Dept Chem, 10550 N Torrey Pines Rd, La Jolla, CA 92037 USA

来源：

CHEMICAL REVIEWS | 2017年 / 117卷 / 13期

基金：

美国国家科学基金会; 美国国家卫生研究院;

关键词：

UNACTIVATED C(SP(3))-H BONDS; CROSS-COUPLING REACTIONS; ALPHA-AMINO-ACIDS; ALIPHATIC CARBON-ATOMS; O-ALLYL ETHERS; DIRECTING-GROUP; STEREOSELECTIVE-SYNTHESIS; DIRECT ARYLATION; BETA-C(SP(3))-H ARYLATION; INTERMOLECULAR AMINATION;

D O I：

10.1021/acs.chemrev.6b00622

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This Review summarizes the advancements in Pd-catalyzed C(sp(3))-H activation via various redox manifolds, including Pd(0)/Pd(II), Pd(II)/Pd(W), and Pd(II)/Pd(0). While few examples have been reported in the activation of alkane C -H bonds, many C(sp(3))-H activation/C-C and C-heteroatom bond forming reactions have been developed by the use of directing group strategies to control regioselectivity and build structural patterns for synthetic chemistry. A number of mono- and bidentate ligands have also proven to be effective for accelerating C(sp(3))-H activation, directed by weakly coordinating auxiliaries, which provides great opportunities to control reactivity and selectivity (including enantioselectivity) in Pd-catalyzed C-H functionalization reactions.

引用

页码：8754 / 8786

页数：33

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