Sulfonic acid functionalized covalent organic frameworks as efficient catalyst for the one-pot tandem reactions

被引:12
作者
Gong, Kai [1 ]
Li, Cunhao [1 ]
Zhang, Daquan [1 ]
Lu, Huilin [1 ]
Wang, Yunyun [1 ]
Li, Haoran [1 ]
Zhang, Huimin [1 ]
机构
[1] Jiangnan Univ, Sch Pharmaceut Sci, Wuxi 214122, Jiangsu, Peoples R China
来源
MOLECULAR CATALYSIS | 2022年 / 519卷
基金
中国国家自然科学基金;
关键词
Covalent organic frameworks; Acidic catalyst; Benzimidazoles; Benzodiazepines; Reductive amination; MULTICOMPONENT SYNTHESIS; ENVIRONMENTALLY BENIGN; REDUCTIVE AMINATION; GREEN SYNTHESIS; DERIVATIVES; BENZIMIDAZOLES; HETEROCYCLES; PERFORMANCE;
D O I
10.1016/j.mcat.2022.112139
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A covalent organic framework containing hydroxyl groups (HO-COF) has been predesigned and synthesized by the cyclotrimerization reaction of acetyls, which was used as a pre-established network to introduce propyl sulfonic acid through post-synthetic modification strategy, for the fabrication of SO3H-COF with graphene-like multilayer structure. SO3H-COF was employed as an effective heterogeneous catalyst for the synthesis of benzimidazoles, the synthesis of benzodiazepines and one-pot reductive amination of carbonyl compounds. The results indicated that the developed protocol has several advantages, such as high activity, broad substrate scope, short reaction time and excellent yields. The distinctive structures of SO3H-COF endowed the fantastic catalytic properties, good stability and circulation performance.
引用
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页数:8
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