Voltage-Induced Payload Release and Wettability Control on TiO2 and TiO2 Nanotubes

被引:114
作者
Song, Yan-Yan [1 ]
Roy, Poulomi [1 ]
Paramasivam, Indhumati [1 ]
Schmuki, Patrik [1 ]
机构
[1] Univ Erlangen Nurnberg, Dept Mat Sci WW 4, LKO, D-91058 Erlangen, Germany
关键词
electrochemistry; photocatalysis; radicals; Schottky barrier; titanium dioxide; PHOTOCATALYSIS; LAYERS; LIGHT; WATER;
D O I
10.1002/anie.200905111
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
"Chemical Equation Presented" Please release me: Hydrocarbon monolayers attached to a TiO2 surface can be cut by electrochemical means, thus allowing active molecules or proteins to be released from the TiO2 surface (see picture). Requirements are suitable electronic properties of TiO2 combined with a voltage to cause Schottky barrier breakdown: valence band holes are then sufficiently reactive to generate OH- radicals. © 2010 Wiley-VCH Verlag GmbH &. Co. KCaA.
引用
收藏
页码:351 / 354
页数:4
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