Microwave-assisted synthesis of metalloporphyrazines

被引：7

作者：

Chandrasekharam, M. ^{[1
]}

Rao, Ch. Srinivasa

Singha, Surya P.

Kantam, M. Lakshmi

Reddy, M. Ramesh

Reddy, P. Yella

Toru, T.

机构：

[1] Indian Inst Chem Technol, Inorgan & Phys Chem Div, Hyderabad 500007, Andhra Pradesh, India

[2] Nagoya Inst Technol, Grad Sch Engn, Dept Appl Chem, Showa Ku, Nagoya, Aichi 4468555, Japan

来源：

TETRAHEDRON LETTERS | 2007年 / 48卷 / 14期

关键词：

maleonitriles; microwave irradiation; substituted octaminoporphyrazines; octakis(alkyl-thio)porphyrazines;

D O I：

10.1016/j.tetlet.2007.02.007

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis of metalloporphyrazines with enhanced yields directly from substituted maleonitriles is described. The one-step procedure involves tetramerization using hexamethyldisilazane, p-toluenesulfonic acid and DMF in a sealed tube under microwave irradiation. The reaction time has been drastically reduced from 24 h by classical oil-bath heating to just 15 min. (c) 2007 Elsevier Ltd. All rights reserved.

引用

页码：2627 / 2630

页数：4

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