Phase behavior and rheology of emulsions in an alkaline/cosolvent/crude oil/brine system

被引:9
作者
Bahmanabadi, H. [1 ]
Hemmati, M. [2 ]
Shariatpanahi, H. [2 ]
Masihi, M. [3 ]
Karambeigi, M. S. [4 ]
机构
[1] Islamic Azad Univ, Fac Petr & Gas Engn, Sci & Res Branch, Tehran, Iran
[2] Res Inst Petr Ind, Polymer Sci & Technol Div, Tehran, Iran
[3] Sharif Univ Technol, Chem & Petr Engn Dept, Tehran, Iran
[4] IOR EOR Res Inst, Tehran, Iran
关键词
Alkaline flooding; cosolvent-phase behavior-rheology; enhanced oil recovery; INTERFACIAL-TENSION; OIL; SURFACTANT;
D O I
10.1080/10916466.2015.1017648
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
Phase behavior of active crude oil/alkaline was systematically studied in the presence of cosolvents. For this purpose, several factors have been considered: alkaline concentration, oil concentration, and type of brine. The best composition was used to generate emulsion for rheology and displacement tests. Furthermore, precipitation of alkaline was eliminated by its synergy with EDTA. Next, rheology of emulsion was analyzed by which a Power law model was developed that indicates non-Newtonian behavior of emulsion. Moreover, the viscosity of emulsion was reduced by the addition of cosolvent as well as by the increase of alkaline concentration. Finally, the best formulation (containing iso-butanol as cosolvent) in the accompaniment with polymer was prepared to be flooded into a sandpack medium. The result was promising so that approximately 40% of original oil in place could be incrementally recovered.
引用
收藏
页码:207 / 215
页数:9
相关论文
共 18 条
[1]   Transient interfacial tension behavior between acidic oils and alkaline solutions [J].
Ball, SD ;
Hornof, V ;
Neale, GH .
CHEMICAL ENGINEERING COMMUNICATIONS, 1996, 147 :145-156
[2]   Evaluation of Chemicals Interaction with Heavy Crude Oil through Water/Oil Emulsion and Interfacial Tension Study [J].
Dehghan, A. A. ;
Masihi, M. ;
Ayatollahi, Sh. .
ENERGY & FUELS, 2013, 27 (10) :5852-5860
[3]   INTERFACIAL ACTIVITIES AND PORPHYRIN CONTENTS OF PETROLEUM EXTRACTS [J].
DUNNING, HN ;
MOORE, JW ;
DENEKAS, MO .
INDUSTRIAL AND ENGINEERING CHEMISTRY, 1953, 45 (08) :1759-1765
[4]  
Fortenberry RP, 2013, SPE ANN TECHN C EXH
[5]   MULTIPHASE MICRO-EMULSION SYSTEMS [J].
HEALY, RN ;
REED, RL ;
STENMARK, DG .
SOCIETY OF PETROLEUM ENGINEERS JOURNAL, 1976, 16 (03) :147-160
[6]   Recent Advances in Surfactant EOR [J].
Hirasaki, George J. ;
Miller, Clarence A. ;
Puerto, Maura .
SPE JOURNAL, 2011, 16 (04) :889-907
[7]  
Ikoku C., 1978, Transient Flow of Non-Newtonian Power-Law Fluids In Porous Material
[8]  
Johnson C. E. Jr., 1976, SPE J, V28, P85
[9]  
Kon W., 2002, SPE E REG M LEX KY O
[10]   Synergy of alkali and surfactant in emulsification of heavy oil in brine [J].
Liu, Q ;
Dong, MZ ;
Yue, XG ;
Hou, JR .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2006, 273 (1-3) :219-228