Synthesis and electropolymerisation of 3,4-alkylenedioxythiophenes

被引：5

作者：

Czardybon, A

Domagala, W

Lapkowski, M

机构：

[1] Silesian Tech Univ, Dept Chem, PL-44100 Gliwice, Poland

[2] Polish Acad Sci, Inst Coal Chem, PL-44121 Gliwice, Poland

来源：

SYNTHETIC METALS | 2003年 / 135卷 / 1-3期

关键词：

heterocycle synthesis; electropolymerisation; compounds formation; electrochemical method;

D O I：

10.1016/S0379-6779(02)00684-7

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

We prepared 2,3,4,5-tetrahydrothieno[3,4-b][1,4]dioxocine - BuDOT and [3,4-b][3',4'-1]-dithieno-1,4,11,14-tetraoxacycloeicosane. We tried to electropolymerise both and found that while BuDOT polymerises easily the second monomer shows difficulty polymerising in organic solvents used. Electrochemical stability of PBuDOT was investigated using cyclic voltammetry and the polymer was found to be stable in the (-0.6 V) similar to 1.55 V potential range.

引用

页码：27 / 28

页数：2

共 6 条

[1]

Bayer A.G., 1988, European Patent, Patent No. [0339340A2, 0339340, 339-340, 339340]

[2] ELECTROCHEMICAL AND SPECTROSCOPIC CHARACTERIZATION OF POLYALKYLENEDIOXYTHIOPHENES [J].