The SF5Ox radicals, x=0-3

被引：13
作者：
Kronberg, M
von Ahsen, S
Willner, H
Francisco, JS
机构：
[1] Berg Univ Gesamthsch Wuppertal, Fachbereich C Anorgan Chem, D-42097 Wuppertal, Germany
[2] Purdue Univ, Dept Chem Earth & Atmospher Sci, W Lafayette, IN 47907 USA
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 02期
关键词：
atmospheric chemistry; matrix isolation; radicals; sulfur fluorides; vibrational spectroscopy;
D O I：
10.1002/anie.200461235
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
No longer up in the air: The radicals SF5Ox (x = 0-3) were isolated in a matrix and characterized by IR and UV spectroscopy, photolysis experiments, and quantum chemical calculations. They are probably involved in the atmospheric oxidation of SF6, a gas commonly used in the electric-power industry.
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页码：253 / 257
页数：5
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