Synthesis of Bimetallic Uranium and Neptunium Complexes of a Binucleating Macrocycle and Determination of the Solid-State Structure by Magnetic Analysis

被引：39

作者：

Arnold, Polly L. ^{[1
]}

Potter , Natalie A. ^{[1
]}

Magnani, Nicola ^{[2
]}

Apostolidis, Christos ^{[2
]}

Griveau, Jean-Christophe ^{[2
]}

Colineau, Eric ^{[2
]}

Morgenstern, Alfred ^{[2
]}

Caciuffo, Roberto ^{[2
]}

Love, Jason B. ^{[1
]}

机构：

[1] Univ Edinburgh, Sch Chem, Edinburgh EH9 3JJ, Midlothian, Scotland

[2] European Commiss, Joint Res Ctr, Inst Transuranium Elements, D-76125 Karlsruhe, Germany

来源：

INORGANIC CHEMISTRY | 2010年 / 49卷 / 12期

关键词：

SINGLE-MOLECULE MAGNETS; SCHIFF-BASE; ACTINIDE; LANTHANIDE; OXO;

D O I：

10.1021/ic100374j

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Syntheses of the bimetallic uranium(III) and neptunium(III) complexes [(Ul)(2)(L)], [(Npl)(2)(L)], and [{U(BH4)}(2)(L)] of the Schiff-base pyrrole macrocycles L are described. In the absence of single-crystal, structural data, fitting of the variable-temperature solid-state magnetic data allows the prediction of polymeric structures for these compounds in the solid state.

引用

页码：5341 / 5343

页数：3

共 28 条

[1] Mononuclear lanthanide single-molecule magnets based on polyoxometalates [J].

AlDamen, Murad A. ;

Clemente-Juan, Juan M. ;

Coronado, Eugenio ;

Marti-Gastaldo, Carlos ;

Gaita-Arino, Alejandro .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (28) :8874-+

[2] Uranyl complexation by a schiff-base, polypyrrolic macrocycle [J].

Arnold, PL ;

Blake, AJ ;

Wilson, C ;

Love, JB .

INORGANIC CHEMISTRY, 2004, 43 (26) :8206-8208

[3] Reduction and selective oxo group silylation of the uranyl dication [J].

Arnold, Polly L. ;

Patel, Dipti ;

Wilson, Claire ;

Love, Jason B. .

NATURE, 2008, 451 (7176) :315-U3

[4] Selective oxo functionalization of the uranyl ion with 3d metal cations [J].

Arnold, Polly L. ;

Patel, Dipti ;

Blake, Alexander J. ;

Wilson, Claire ;

Love, Jason B. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (30) :9610-9611

[5] A CONVENIENT ENTRY INTO TRIVALENT ACTINIDE CHEMISTRY - SYNTHESIS AND CHARACTERIZATION OF ANI3(THF)4 AND AN[N(SIME3)2]3 (AN=U, NP, PU) [J].

AVENS, LR ;

BOTT, SG ;

CLARK, DL ;

SATTELBERGER, AP ;

WATKIN, JG ;

ZWICK, BD .

INORGANIC CHEMISTRY, 1994, 33 (10) :2248-2256

[6] PREPARATION AND PROPERTIES OF ACTINIDE BOROHYDRIDES - PA(BH4)4, NP(BH4)4, AND PU(BH4)4 [J].

BANKS, RH ;

EDELSTEIN, NM ;

RIETZ, RR ;

TEMPLETON, DH ;

ZALKIN, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (06) :1957-1958

[7] Computational Density Functional Study of Polypyrrolic Macrocycles: Analysis of Actinyl-Oxo to 3d Transition Metal Bonding [J].

Berard, Joel J. ;

Schreckenbach, Georg ;

Arnold, Polly L. ;

Patel, Dipti ;

Love, Jason B. .

INORGANIC CHEMISTRY, 2008, 47 (24) :11583-11592

[8] Actinide uptake by transferrin and ferritin metalloproteins [J].

Den Auwer, C ;

Llorens, I ;

Moisy, P ;

Vidaud, C ;

Goudard, F ;

Barbot, C ;

Solari, PL ;

Funke, H .

RADIOCHIMICA ACTA, 2005, 93 (11) :699-703

[9] Design and synthesis of binucleating macrocyclic clefts derived from Schiff-base calixpyrroles [J].

Givaja, Gonzalo ;

Volpe, Manuel ;

Leeland, James W. ;

Edwards, Michael A. ;

Young, Thomas K. ;

Darby, S. Barnie ;

Reid, Stuart D. ;

Blake, Alexander J. ;

Wilson, Claire ;

Wolowska, Joanna ;

McInnes, Eric J. L. ;

Schroeder, Martin ;

Love, Jason B. .

CHEMISTRY-A EUROPEAN JOURNAL, 2007, 13 (13) :3707-3723

[10] Lanthanide double-decker complexes functioning as magnets at the single-molecular level [J].

Ishikawa, N ;

Sugita, M ;

Ishikawa, T ;

Koshihara, S ;

Kaizu, Y .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (29) :8694-8695

← 1 2 3 →