Fast Colorimetric Assay for Screening NSR Catalyst

被引:5
作者
Park, Joo-Hyoung [2 ]
Park, Sang Jun [1 ]
Nam, In-Sik [1 ]
机构
[1] Pohang Univ Sci & Technol POSTECH, Sch Environm Sci & Engn, Pohang, South Korea
[2] Res Inst Ind Sci & Technol RIST, CO2 Project Team, Pohang 790330, South Korea
关键词
Combinatorial approach; Colorimetric assay; DeNOx; NSR (NOx storage-reduction); NOX STORAGE-REDUCTION; SELECTIVE REDUCTION; COMBINATORIAL LIBRARIES; HETEROGENEOUS CATALYSTS; SULFUR DEACTIVATION; COMBUSTION ENGINES; NITROGEN-OXIDES; 3-WAY CATALYST; NO(X) STORAGE; FT-IR;
D O I
10.1007/s10563-009-9083-7
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The NSR (NOx storage and reduction) technology is one of the most promising methods for removing NOx from next-generation lean-burn and diesel engines. Three major drawbacks, including the low temperature activity, the catalyst sulfur tolerance and the use of the large amount of the noble metals for the commercial application of NSR catalytic system, may be resolved by the development of a better catalytic system through a fast assay method in line with the combinatorial chemistry technique. The colorimetric method is the most effective way for screening a large number of the catalyst samples at once, although an appropriate dye for revealing the color specific to NOx should be examined in advance. A knowledge-based colorimetric methodology for screening a better NSR catalyst by combinatorial approach has been developed and validated by the experimental results determined by means of traditional, time-consuming techniques such as TPD.
引用
收藏
页码:11 / 20
页数:10
相关论文
共 67 条
[1]   Influence of the type of reducing agent (H2, CO, C3H6 and C3H8) on the reduction of stored NOX in a Pt/BaO/Al2O3 model catalyst [J].
Abdulhamid, H ;
Fridell, E ;
Skoglundh, M .
TOPICS IN CATALYSIS, 2004, 30-1 (1-4) :161-168
[2]   Investigations of sulphur deactivation of NOx storage catalysts:: influence of sulphur carrier and exposure conditions [J].
Amberntsson, A ;
Skoglundh, M ;
Jonsson, M ;
Fridell, E .
CATALYSIS TODAY, 2002, 73 (3-4) :279-286
[3]   Control of NOx emissions from diesel engine by selective catalytic reduction (SCR) with urea [J].
Baik, JH ;
Yim, SD ;
Nam, IS ;
Mok, YS ;
Lee, JH ;
Cho, BK ;
Oh, SH .
TOPICS IN CATALYSIS, 2004, 30-1 (1-4) :37-41
[4]   A review of the selective reduction of NOx, with hydrocarbons under lean-burn conditions with non-zeolitic oxide and platinum group metal catalysts [J].
Burch, R ;
Breen, JP ;
Meunier, FC .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2002, 39 (04) :283-303
[5]   Knowledge and know-how in emission control for mobile applications [J].
Burch, R .
CATALYSIS REVIEWS-SCIENCE AND ENGINEERING, 2004, 46 (3-4) :271-333
[6]   Application of a new color detection based method for the fast parallel screening of DeNOx catalysts [J].
Busch, OM ;
Hoffmann, C ;
Johann, TRF ;
Schmidt, HW ;
Strehlau, W ;
Schüth, F .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (45) :13527-13532
[7]   The storage of nitrogen oxides on alumina-supported barium oxide [J].
Cant, NW ;
Patterson, MJ .
CATALYSIS TODAY, 2002, 73 (3-4) :271-278
[8]   Fe-Ce-ZSM-5 a new catalyst of outstanding properties in the selective catalytic reduction of NO with NH3 [J].
Carja, G ;
Delahay, G ;
Signorile, C ;
Coq, B .
CHEMICAL COMMUNICATIONS, 2004, (12) :1404-1405
[9]   Study of the effect of Ba loading for catalytic activity of Pt-Ba/Al2O3 model catalysts [J].
Castoldi, L ;
Nova, I ;
Lietti, L ;
Forzatti, P .
CATALYSIS TODAY, 2004, 96 (1-2) :43-52
[10]   gamma-alumina-supported Pt catalysts for aromatics reduction: A structural investigation of sulfur poisoning catalyst deactivation [J].
Chang, JR ;
Chang, SL ;
Lin, TB .
JOURNAL OF CATALYSIS, 1997, 169 (01) :338-346