In situ photoemission spectroscopy study on formation of HfO2 dielectrics on epitaxial graphene on SiC substrate

被引:11
作者
Chen, Q. [1 ]
Huang, H. [1 ]
Chen, W. [1 ]
Wee, A. T. S. [1 ]
Feng, Y. P. [1 ]
Chai, J. W. [2 ]
Zhang, Z. [2 ]
Pan, J. S. [2 ]
Wang, S. J. [2 ]
机构
[1] Natl Univ Singapore, Dept Phys, Singapore 117542, Singapore
[2] ASTAR, Inst Mat Res & Engn, Singapore 117602, Singapore
关键词
core levels; hafnium compounds; heat treatment; high-k dielectric thin films; plasma materials processing; semiconductor heterojunctions; semiconductor-insulator boundaries; spectral line shift; sputter deposition; surface chemistry; thermal stability; X-ray photoelectron spectra; PRECISE DETERMINATION; 6H-SIC(0001); GROWTH;
D O I
10.1063/1.3327834
中图分类号
O59 [应用物理学];
学科分类号
摘要
High quality HfO2 dielectrics have been grown on epitaxial graphene on 4H-SiC substrates and have been studied by using in situ x-ray photoemission spectroscopy. The in situ thermal treatment shows that the HfO2/graphene/4H-SiC heterojunctions have good thermal stability up to 650 degrees C. A shift of core-level spectra from graphene layer implies that charge transfer takes place at the interface. The high thermal stability and sufficient barrier heights between HfO2 and graphene indicate that high-k dielectric grown on graphene is very promising for the development of graphene-based electronic devices.
引用
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页数:3
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共 22 条
[1]   Electronic confinement and coherence in patterned epitaxial graphene [J].
Berger, Claire ;
Song, Zhimin ;
Li, Xuebin ;
Wu, Xiaosong ;
Brown, Nate ;
Naud, Cecile ;
Mayou, Didier ;
Li, Tianbo ;
Hass, Joanna ;
Marchenkov, Atexei N. ;
Conrad, Edward H. ;
First, Phillip N. ;
de Heer, Wait A. .
SCIENCE, 2006, 312 (5777) :1191-1196
[2]   Ultrahigh electron mobility in suspended graphene [J].
Bolotin, K. I. ;
Sikes, K. J. ;
Jiang, Z. ;
Klima, M. ;
Fudenberg, G. ;
Hone, J. ;
Kim, P. ;
Stormer, H. L. .
SOLID STATE COMMUNICATIONS, 2008, 146 (9-10) :351-355
[3]   Band offsets of HfO2/ZnO interface: In situ x-ray photoelectron spectroscopy measurement and ab initio calculation [J].
Chen, Q. ;
Yang, M. ;
Feng, Y. P. ;
Chai, J. W. ;
Zhang, Z. ;
Pan, J. S. ;
Wang, S. J. .
APPLIED PHYSICS LETTERS, 2009, 95 (16)
[4]   Band alignment and thermal stability of HfO2 gate dielectric on SiC [J].
Chen, Q. ;
Feng, Y. P. ;
Chai, J. W. ;
Zhang, Z. ;
Pan, J. S. ;
Wang, S. J. .
APPLIED PHYSICS LETTERS, 2008, 93 (05)
[5]   Growth of monodispersed cobalt nanoparticles on 6H-SiC(0001) honeycomb template [J].
Chen, W ;
Loh, KP ;
Xu, H ;
Wee, ATS .
APPLIED PHYSICS LETTERS, 2004, 84 (02) :281-283
[6]   Atomic structure of the 6H-SiC(0001) nanomesh [J].
Chen, W ;
Xu, H ;
Liu, L ;
Gao, XY ;
Qi, DC ;
Peng, GW ;
Tan, SC ;
Feng, YP ;
Loh, KP ;
Wee, ATS .
SURFACE SCIENCE, 2005, 596 (1-3) :176-186
[7]   Surface transfer p-type doping of epitaxial graphene [J].
Chen, Wei ;
Chen, Shi ;
Qi, Dong Chen ;
Gao, Xing Yu ;
Wee, Andrew Thye Shen .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (34) :10418-10422
[8]   Extremely high thermal conductivity of graphene: Prospects for thermal management applications in nanoelectronic circuits [J].
Ghosh, S. ;
Calizo, I. ;
Teweldebrhan, D. ;
Pokatilov, E. P. ;
Nika, D. L. ;
Balandin, A. A. ;
Bao, W. ;
Miao, F. ;
Lau, C. N. .
APPLIED PHYSICS LETTERS, 2008, 92 (15)
[9]   Bottom-up Growth of Epitaxial Graphene on 6H-SiC(0001) [J].
Huang, Han ;
Chen, Wei ;
Chen, Shi ;
Wee, Andrew Thye Shen .
ACS NANO, 2008, 2 (12) :2513-2518
[10]   Epitaxial graphene transistors on SIC substrates [J].
Kedzierski, Jakub ;
Hsu, Pei-Lan ;
Healey, Paul ;
Wyatt, Peter W. ;
Keast, Craig L. ;
Sprinkle, Mike ;
Berger, Claire ;
de Heer, Walt A. .
IEEE TRANSACTIONS ON ELECTRON DEVICES, 2008, 55 (08) :2078-2085