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In situ photoemission spectroscopy study on formation of HfO2 dielectrics on epitaxial graphene on SiC substrate
被引:11
作者:

Chen, Q.
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Natl Univ Singapore, Dept Phys, Singapore 117542, Singapore Natl Univ Singapore, Dept Phys, Singapore 117542, Singapore

Huang, H.
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Natl Univ Singapore, Dept Phys, Singapore 117542, Singapore Natl Univ Singapore, Dept Phys, Singapore 117542, Singapore

Chen, W.
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Natl Univ Singapore, Dept Phys, Singapore 117542, Singapore Natl Univ Singapore, Dept Phys, Singapore 117542, Singapore

Wee, A. T. S.
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Natl Univ Singapore, Dept Phys, Singapore 117542, Singapore Natl Univ Singapore, Dept Phys, Singapore 117542, Singapore

Feng, Y. P.
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Natl Univ Singapore, Dept Phys, Singapore 117542, Singapore Natl Univ Singapore, Dept Phys, Singapore 117542, Singapore

Chai, J. W.
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ASTAR, Inst Mat Res & Engn, Singapore 117602, Singapore Natl Univ Singapore, Dept Phys, Singapore 117542, Singapore

Zhang, Z.
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ASTAR, Inst Mat Res & Engn, Singapore 117602, Singapore Natl Univ Singapore, Dept Phys, Singapore 117542, Singapore

Pan, J. S.
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ASTAR, Inst Mat Res & Engn, Singapore 117602, Singapore Natl Univ Singapore, Dept Phys, Singapore 117542, Singapore

Wang, S. J.
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ASTAR, Inst Mat Res & Engn, Singapore 117602, Singapore Natl Univ Singapore, Dept Phys, Singapore 117542, Singapore
机构:
[1] Natl Univ Singapore, Dept Phys, Singapore 117542, Singapore
[2] ASTAR, Inst Mat Res & Engn, Singapore 117602, Singapore
关键词:
core levels;
hafnium compounds;
heat treatment;
high-k dielectric thin films;
plasma materials processing;
semiconductor heterojunctions;
semiconductor-insulator boundaries;
spectral line shift;
sputter deposition;
surface chemistry;
thermal stability;
X-ray photoelectron spectra;
PRECISE DETERMINATION;
6H-SIC(0001);
GROWTH;
D O I:
10.1063/1.3327834
中图分类号:
O59 [应用物理学];
学科分类号:
摘要:
High quality HfO2 dielectrics have been grown on epitaxial graphene on 4H-SiC substrates and have been studied by using in situ x-ray photoemission spectroscopy. The in situ thermal treatment shows that the HfO2/graphene/4H-SiC heterojunctions have good thermal stability up to 650 degrees C. A shift of core-level spectra from graphene layer implies that charge transfer takes place at the interface. The high thermal stability and sufficient barrier heights between HfO2 and graphene indicate that high-k dielectric grown on graphene is very promising for the development of graphene-based electronic devices.
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