Stepwise hydrolysis of aluminum chloride iodide LAlClI (L = HC[(CMe)(NAr)]2, Ar=2,6-iPr2C6H3) in the presence of N-heterocyclic carbene as hydrogen halide acceptor

被引：35

作者：

Zhu, HP ^{[1
]}

Chai, JF ^{[1
]}

He, C ^{[1
]}

Bai, GC ^{[1
]}

Roesky, HW ^{[1
]}

Jancik, V ^{[1
]}

Schmidt, HG ^{[1
]}

Noltemeyer, M ^{[1
]}

机构：

[1] Univ Gottingen, Inst Anorgan Chem, D-37077 Gottingen, Germany

来源：

ORGANOMETALLICS | 2005年 / 24卷 / 03期

关键词：

D O I：

10.1021/om049339a

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The aluminum chloride iodide LAlClI (2, L = HC[(CMe)(NAr)](2), Ar = 2,6-iPr(2)C(6)H(3)) has been synthesized to study the stepwise hydrolysis of this compound in the presence of 1,3diisopropyl-4,5-dimethylimidazol-2-ylidene as hydrogen halide acceptor. The isolation and characterization of the aluminum chloride hydroxide [LAlCl(mu-OH)](2) (3) and the dihydroxide LAl(OH)(2) (4) demonstrate the realization of a controlled hydrolysis.

引用

页码：380 / 384

页数：5