Stepwise hydrolysis of aluminum chloride iodide LAlClI (L = HC[(CMe)(NAr)]2, Ar=2,6-iPr2C6H3) in the presence of N-heterocyclic carbene as hydrogen halide acceptor

被引：35
作者：
Zhu, HP [1 ]
Chai, JF [1 ]
He, C [1 ]
Bai, GC [1 ]
Roesky, HW [1 ]
Jancik, V [1 ]
Schmidt, HG [1 ]
Noltemeyer, M [1 ]
机构：
[1] Univ Gottingen, Inst Anorgan Chem, D-37077 Gottingen, Germany
来源：
ORGANOMETALLICS | 2005年 / 24卷 / 03期
关键词：
D O I：
10.1021/om049339a
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The aluminum chloride iodide LAlClI (2, L = HC[(CMe)(NAr)](2), Ar = 2,6-iPr(2)C(6)H(3)) has been synthesized to study the stepwise hydrolysis of this compound in the presence of 1,3diisopropyl-4,5-dimethylimidazol-2-ylidene as hydrogen halide acceptor. The isolation and characterization of the aluminum chloride hydroxide [LAlCl(mu-OH)](2) (3) and the dihydroxide LAl(OH)(2) (4) demonstrate the realization of a controlled hydrolysis.
引用
收藏
页码：380 / 384
页数：5
相关论文
共 52 条
  • [1] Bai G., 2003, ANGEW CHEM, V115, P1164
  • [2] Synthesis, structural characterization, and reaction of the first terminal hydroxide-containing alumoxane with an [{Al(OH)}2(μ-O)] core
    Bai, GC
    Roesky, HW
    Li, JY
    Noltemeyer, M
    Schmidt, HG
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (44) : 5502 - 5506
  • [3] Aluminum dihydroxide with terminal OH groups: an unprecedented congener of boronic acid
    Bai, GC
    Peng, Y
    Roesky, HW
    Li, JY
    Schmidt, HG
    Noltemeyer, M
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (10) : 1132 - 1135
  • [4] Bai GC, 2003, ANGEW CHEM, V115, P5660
  • [5] COMPLEXES OF BIS(CHLOROMETHYL)ALUMOXANE WITH ETHYL ETHER AND BENZONITRILE
    BOLESLAWSKI, M
    PASYNKIE.S
    MINORSKA, A
    HRYNIOW, W
    [J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1974, 65 (02) : 165 - 167
  • [6] Brintzinger H. H., 1995, ANGEW CHEM, V107, P1255
  • [7] STEREOSPECIFIC OLEFIN POLYMERIZATION WITH CHIRAL METALLOCENE CATALYSTS
    BRINTZINGER, HH
    FISCHER, D
    MULHAUPT, R
    RIEGER, B
    WAYMOUTH, RM
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1995, 34 (11) : 1143 - 1170
  • [8] Budzelaar PHM, 1998, EUR J INORG CHEM, P1485
  • [9] First isolation and structural characterization of triarylaluminum-water and -methanol complexes
    Chakraborty, D
    Chen, EYX
    [J]. ORGANOMETALLICS, 2003, 22 (01) : 207 - 210
  • [10] THE POLYMERIZATION OF EPOXIDES BY METAL HALIDE CATALYSTS
    COLCLOUGH, RO
    GEE, G
    HIGGINSON, WCE
    JACKSON, JB
    LITT, M
    [J]. JOURNAL OF POLYMER SCIENCE, 1959, 34 (127): : 171 - 179
123456