Discovery, synthesis, and characterization of an isomeric coordination polymer with pillared kagome net topology

被引：86

作者：

Chun, Hyungphil ^{[1
]}

Moon, Jumi ^{[1
]}

机构：

[1] Hanyang Univ, Coll Sci & Technol, Dept Appl Chem, Ansan 426791, South Korea

来源：

INORGANIC CHEMISTRY | 2007年 / 46卷 / 11期

关键词：

D O I：

10.1021/ic070036t

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A topological isomer based on Zn-2 paddlewheel, dicarboxylate, and diamine ligands is synthesized by solvothermal methods after careful modulation of the reaction conditions. The new framework is characterized by a pillared Kagome net topology and possesses a sustainable pore structure with high surface area (similar to 2400 m(2)/g) and large hexagonal channels (similar to 15 angstrom).

引用

页码：4371 / 4373

页数：3

共 52 条

[1] VIII(OH){O2C-C6H4-CO2}•(HO2C-C6H4-CO2H)x(DMF)y(H2O)z (or MIL-68), a new vanadocarboxylate with a large pore hybrid topology:: reticular synthesis with infinite inorganic building blocks? [J].

Barthelet, K ;

Marrot, J ;

Férey, G ;

Riou, D .

CHEMICAL COMMUNICATIONS, 2004, (05) :520-521

[2] Synthesis and magnetic properties of an amine-templated Fe2+ (S=2) sulfate with a distorted Kagome structure [J].

Behera, J. N. ;

Rao, C. N. R. .

INORGANIC CHEMISTRY, 2006, 45 (23) :9475-9479

[3] Interpenetrating metal-organic and inorganic 3D networks: a computer-aided systematic investigation. Part I. Analysis of the Cambridge structural database [J].

Blatov, VA ;

Carlucci, L ;

Ciani, G ;

Proserpio, DM .

CRYSTENGCOMM, 2004, 6 :377-395

[4] Design, chirality, and flexibility in nanoporous molecule-based materials [J].

Bradshaw, D ;

Claridge, JB ;

Cussen, EJ ;

Prior, TJ ;

Rosseinsky, MJ .

ACCOUNTS OF CHEMICAL RESEARCH, 2005, 38 (04) :273-282

[5] Permanent microporosity and enantioselective sorption in a chiral open framework [J].

Bradshaw, D ;

Prior, TJ ;

Cussen, EJ ;

Claridge, JB ;

Rosseinsky, MJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (19) :6106-6114

[6] A microporous metal-organic framework for gas-chromatographic separation of alkanes [J].

Chen, BL ;

Liang, CD ;

Yang, J ;

Contreras, DS ;

Clancy, YL ;

Lobkovsky, EB ;

Yaghi, OM ;

Dai, S .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (09) :1390-1393

[7] High H2 adsorption in a microporous metal-organic framework with open metal sites [J].

Chen, BL ;

Ockwig, NW ;

Millward, AR ;

Contreras, DS ;

Yaghi, OM .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (30) :4745-4749

[8] Synthesis, X-ray crystal structures, and gas sorption properties of pillared square grid nets based on paddle-wheel motifs: Implications for hydrogen storage in porous materials [J].

Chun, H ;

Dybtsev, DN ;

Kim, H ;

Kim, K .

CHEMISTRY-A EUROPEAN JOURNAL, 2005, 11 (12) :3521-3529

[9] Hydrogen adsorption in a nickel based coordination polymer with open metal sites in the cylindrical cavities of the desolvated framework [J].

Dietzel, PDC ;

Panella, B ;

Hirscher, M ;

Blom, R ;

Fjellvåg, H .

CHEMICAL COMMUNICATIONS, 2006, (09) :959-961

[10] Strong H2 binding and selective gas adsorption within the microporous coordination solid Mg3(O2C-C10H6-CO2)3 [J].

Dinca, M ;

Long, JR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (26) :9376-9377

← 1 2 3 4 5 6 →