(-)-(2R, 3R)-O, O′-dibenzoyl-(2R, 3R)-tartaric acid-hexamethylphosphoramide (1/2)

被引:3
作者
Zhang, Yi-Jian
Shu, Zhan
Feng, Wen-Jie
Li, Mei-Chao
Jin, Zhi-Min [1 ]
机构
[1] Zhejiang Univ Technol, Coll Pharmaceut Sci, Hangzhou 310014, Peoples R China
[2] Hangzhou Normal Univ, Coll Mat Chem & Chem Engn, Hangzhou 310036, Peoples R China
[3] Zhejiang Univ Technol, Coll Chem Engn, Hangzhou 310014, Peoples R China
关键词
D O I
10.1107/S1600536807008380
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, C18H14O8.2C(6)H(18)N(3)OP, one acid and two phosphoramide molecules are linked together by strong O-H...O hydrogen bonds. There are two crystallographically independent amide-acid assemblies in the asymmetric unit. Three of the four symmetry-independent phosphoramide molecules adopt propeller-like conformations. The crystal structure is additionally stabilized by C-H...O interactions.
引用
收藏
页码:O1546 / O1548
页数:3
相关论文
共 15 条
[1]   Dilemmas in crystallization.: The 'unusual' behavior of trans-1,5-dichloro-9,10-diethynyl-9,10-dihydroanthracene-9,10-diol and the more 'normal' behavior of its pseudopolymorphs with dipolar aprotic solvents [J].
Banerjee, R ;
Desiraju, GR ;
Mondal, R ;
Batsanov, AS ;
Broder, CK ;
Howard, JAK .
HELVETICA CHIMICA ACTA, 2003, 86 (05) :1339-1351
[2]  
*BRUK AXS INC, 1998, SHELXTL
[3]   ASYMMETRIC CATALYZES .5. ENANTIOSELECTIVE AMINO-ACID SYNTHESIS BY HYDROGENATION OF PROCHIRAL OLEFINS WITH RH-COMPLEXES OF THE NEW OPTICALLY-ACTIVE CHELATING PHOSPHANE NORPHOS [J].
BRUNNER, H ;
PIERONCZYK, W ;
SCHONHAMMER, B ;
STRENG, K ;
BERNAL, I ;
KORP, J .
CHEMISCHE BERICHTE-RECUEIL, 1981, 114 (03) :1137-1149
[4]   (S)-2,2′,6,6′-tetramethoxy-4.4′-bis(diphenyl-phosphino)-3,3′-bipyridine-(2S,3S)-(+)-dibenzoyl-L-tartaric acid-chloroform (1/1/1) [J].
Chen, H ;
Wu, J ;
Guo, RW ;
Yeung, CH ;
Zhou, ZY .
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2003, 59 :O1254-O1256
[5]   The isolation and structure of a highly stable, metallation-resistant and multiply hydrogen-bonded sulfonylamide-phosphine oxide adduct, PhSO(2)CH(2)C(=O)NH2 center dot O=P(NMe(2))(3), PSA center dot HMPA (PSA=phenylsulfonylacetamide, HMPA=hexamethylphosphoramide) [J].
CraggHine, I ;
Davidson, MG ;
Edwards, AJ ;
Lamb, E ;
Raithby, PR ;
Snaith, R .
CHEMICAL COMMUNICATIONS, 1996, (02) :153-154
[6]   ON ENANTIOMORPH-POLARITY ESTIMATION [J].
FLACK, HD .
ACTA CRYSTALLOGRAPHICA SECTION A, 1983, 39 (NOV) :876-881
[7]   Alcohol-O,O′-dibenzoyl-(2R,3R)-tartaric acid complexes [J].
Kovári, Z ;
Böcskei, Z ;
Kassai, C ;
Fogassy, ER ;
Kozma, D .
CHIRALITY, 2004, 16 :S23-S27
[8]   Study of the diastereoisomers formed between (N-alkyl)-pipecolic acid-anilides and 2R,3R-tartaric acid or O,O'-dibenzoyl-2R,3R-tartaric acid. Do the tartaric acids form molecular-complexes, instead of salts during optical resolutions? [J].
Nemak, K ;
Acs, M ;
Jaszay, ZM ;
Kozma, D ;
Fogassy, E .
TETRAHEDRON, 1996, 52 (05) :1637-1642
[9]   Chiral 1,8-bis(tert-butylphenylphosphino)naphthalene oxides and sulfides:: resolution and structures [J].
Omelanczuk, J ;
Karaçar, A ;
Freytag, M ;
Jones, PG ;
Bartsch, R ;
Mikolajczyk, M ;
Schmutzler, R .
INORGANICA CHIMICA ACTA, 2003, 350 :583-591
[10]  
PAULE S, 2003, EUR J ORG CHEM, P1931