Biological carbon skeleton of lotus-pollen surrounded by rod-like Sb2S3 as anode material in lithium ion battery

被引:21
作者
Ru, Qiang
Chen, Xiaoqiu
Wang, Bei
Guo, Qing
Wang, Zhen
Hou, Xianhua
Hu, Shejun
机构
[1] Guangdong Engn Technol Res Ctr Efficient Green En, Guangzhou 510006, Guangdong, Peoples R China
[2] South China Normal Univ, Sch Phys & Telecommun Engn, Guangdong Prov Key Lab Quantum Engn & Quantum Mat, Guangzhou 510006, Guangdong, Peoples R China
关键词
Sb2S3; Lotus-pollen; Anode material; Lithium ion battery; ENERGY-STORAGE; HIGH-CAPACITY; PERFORMANCE; GRAPHENE; LIFE; HETEROSTRUCTURES; FABRICATION; COMPOSITE; FACILE;
D O I
10.1016/j.matlet.2017.03.180
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The novel Sb2S3/lotus-pollen composites are fabricated for the first time in the literature through hydrothermal method followed by calcination treatment. As an anode material in lithium ion batteries, the Sb2S3/lotus-pollen composites deliver an initial discharge capacity of 988 mA h g(-1) at 100 mA g(-1) and maintain a capacity of 591 mA h g(-1) after 100 cycles. Even up to 1000 and 2000 mA g(-1), the Sb2S3/lotus-pollen composites still obtain capacity of 436 and 365 mA h g(-1), respectively, indicating a good rate capability. Compared with pure Sb2S3, the enhanced electrochemical performance of Sb2S3/lotus-pollen may be ascribed to the improved electron conductivity and volume buffering effect provided by the biological carbon skeleton of lotus-pollen. (C) 2017 Elsevier B.V. All rights reserved.
引用
收藏
页码:57 / 60
页数:4
相关论文
共 20 条
[1]   Cooperative enhancement of capacities in nanostructured SnSb/carbon nanotube network nanocomposite as anode for lithium ion batteries [J].
Fan, Shufen ;
Sun, Ting ;
Rui, Xianhong ;
Yan, Qingyu ;
Hng, Huey Hoon .
JOURNAL OF POWER SOURCES, 2012, 201 :288-293
[2]   Homogeneous CoO on Graphene for Binder-Free and Ultralong-Life Lithium Ion Batteries [J].
Huang, Xiao-lei ;
Wang, Ru-zhi ;
Xu, Dan ;
Wang, Zhong-li ;
Wang, Heng-guo ;
Xu, Ji-jing ;
Wu, Zhong ;
Liu, Qing-chao ;
Zhang, Yu ;
Zhang, Xin-bo .
ADVANCED FUNCTIONAL MATERIALS, 2013, 23 (35) :4345-4353
[3]   Facile and controllable one-pot synthesis of an ordered nanostructure of Co(OH)2 nanosheets and their modification by oxidation for high-performance lithium-ion batteries [J].
Huang, Xiao-lei ;
Zhao, Xue ;
Wang, Zhong-li ;
Wang, Li-min ;
Zhang, Xin-bo .
JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (09) :3764-3769
[4]   Self-assembled large-area Co(OH)2 nanosheets/ionic liquid modified graphene heterostructures toward enhanced energy storage [J].
Huang, Xiao-lei ;
Chai, Jia ;
Jiang, Tao ;
Wei, Ying-Jin ;
Chen, Gang ;
Liu, Wan-qiang ;
Han, Dongxue ;
Niu, Li ;
Wang, Limin ;
Zhang, Xin-bo .
JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (08) :3404-3410
[5]   Self-assembly of ultrathin porous NiO nanosheets/graphene hierarchical structure for high-capacity and high-rate lithium storage [J].
Huang, Yun ;
Huang, Xiao-lei ;
Lian, Jian-she ;
Xu, Dan ;
Wang, Li-min ;
Zhang, Xin-bo .
JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (07) :2844-2847
[6]   Rational Design of MnO/Carbon Nanopeapods with Internal Void Space for High-Rate and Long-Life Li-Ion Batteries [J].
Jiang, Hao ;
Hu, Yanjie ;
Guo, Shaojun ;
Yan, Chaoyi ;
Lee, Pooi See ;
Li, Chunzhong .
ACS NANO, 2014, 8 (06) :6038-6046
[7]   High-performance Sb2S3/Sb anode materials for Li-ion batteries [J].
Kong, Junli ;
Wei, Hang ;
Xia, Dingguo ;
Yu, Pingrong .
MATERIALS LETTERS, 2016, 179 :114-117
[8]   Mesoporous nitrogen-rich carbons derived from protein for ultra-high capacity battery anodes and supercapacitors [J].
Li, Zhi ;
Xu, Zhanwei ;
Tan, Xuehai ;
Wang, Huanlei ;
Holt, Chris M. B. ;
Stephenson, Tyler ;
Olsen, Brian C. ;
Mitlin, David .
ENERGY & ENVIRONMENTAL SCIENCE, 2013, 6 (03) :871-878
[9]   Stibnite (Sb2S3) and its amorphous composite as dual electrodes for rechargeable lithium batteries [J].
Park, Cheol-Min ;
Hwa, Yoon ;
Sung, Nark-Eon ;
Sohn, Hun-Joon .
JOURNAL OF MATERIALS CHEMISTRY, 2010, 20 (06) :1097-1102
[10]   Spherical carbon particles and carbon nanotubes prepared by autogenic reactions: Evaluation as anodes in lithium electrochemical cells [J].
Pol, Vilas G. ;
Thackeray, Michael M. .
ENERGY & ENVIRONMENTAL SCIENCE, 2011, 4 (05) :1904-1912