Synthesis, characterization, and degradation investigation of a novel (1D+2D) coordination polymer

被引：5
|
作者：
Dai, Yu-Mei [1 ]
Liu, Meng-Jia [1 ]
机构：
[1] Minnan Sci & Technol Univ, Inst Chem & Life Sci, Quanzhou 362332, Peoples R China
来源：
INORGANIC AND NANO-METAL CHEMISTRY | 2022年 / 52卷 / 04期
关键词：
Co(II) Coordination polymer; crystal structure; catalysis; degradation property; METAL-ORGANIC FRAMEWORKS; CRYSTAL-STRUCTURE; OXIDATION; LIGAND; CO;
D O I：
10.1080/24701556.2021.1916760
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new compound, {[Co(TPA)(PYIM)(2)(H2O)(2)](MI)(4)}(n)(1)(H(2)TPA = terephthalic acid, PYIM = 2-(3-pyridine) benzimidazole, MI = 2-lmidazolidone) has been urothermal synthesized and structurally characterized by elemental analysis, IR Spectra, the Powder Diffraction and single-crystal X-ray diffraction. Single-crystal X-ray diffraction analysis reveals that the (1 D)+(2D hydrogen bonds) pillar the compound 1 into an open 3 D supramolecular framework with a pore along the b axis (approximate dimensions 4.5 x 15 angstrom(2)), which is occupied by free MI molecules. In addition, the catalytic-degradation capacity of compound 1 for methylene blue (MB) was investigated. Supplemental data for this article can be accessed online at 10.1080/24701556.2021.1916760
引用
收藏
页码：614 / 619
页数：6
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