Rhodium-catalyzed transfer hydrogenation of quinoxalines with water as a hydrogen source

被引：22

作者：

Zhang, Xia ^{[1
,2
]}

Chen, Jingchao ^{[1
,2
]}

Khan, Ruhima ^{[1
,2
]}

Shen, Guoli ^{[1
,2
]}

He, Zhenxiu ^{[1
,2
]}

Zhou, Yongyun ^{[1
,2
,3
]}

Fan, Baomin ^{[1
,2
,3
]}

机构：

[1] Yunnan Minzu Univ, Key Lab Chem Ethn Med Resources, State Ethn Affairs Commiss, Kunming 650500, Yunnan, Peoples R China

[2] Minist Educ, Kunming 650500, Yunnan, Peoples R China

[3] Yunnan Minzu Univ, Sch Chem & Environm, Kunming 650500, Yunnan, Peoples R China

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2019年 / 17卷 / 48期

基金：

中国国家自然科学基金;

关键词：

ASYMMETRIC TRANSFER HYDROGENATION; ALKYNES; REDUCTION; ALKENES; DEUTERIATION; HETEROCYCLES; QUINOLINES; CHEMISTRY; EFFICIENT; ESTER;

D O I：

10.1039/c9ob02095k

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Rhodium-catalyzed transfer hydrogenation of quinoxalines with water as a hydrogen source was reported. The reaction allowed the simple preparation of tetrahydroquinoxalines under mild conditions. The deuterium-labelling experiment confirmed that water is the sole hydrogen source in the transfer hydrogenation reaction.

引用

收藏

页码：10142 / 10147

页数：6

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