Rhodium-catalyzed transfer hydrogenation of quinoxalines with water as a hydrogen source

被引：21
作者：
Zhang, Xia [1 ,2 ]
Chen, Jingchao [1 ,2 ]
Khan, Ruhima [1 ,2 ]
Shen, Guoli [1 ,2 ]
He, Zhenxiu [1 ,2 ]
Zhou, Yongyun [1 ,2 ,3 ]
Fan, Baomin [1 ,2 ,3 ]
机构：
[1] Yunnan Minzu Univ, Key Lab Chem Ethn Med Resources, State Ethn Affairs Commiss, Kunming 650500, Yunnan, Peoples R China
[2] Minist Educ, Kunming 650500, Yunnan, Peoples R China
[3] Yunnan Minzu Univ, Sch Chem & Environm, Kunming 650500, Yunnan, Peoples R China
来源：
ORGANIC & BIOMOLECULAR CHEMISTRY | 2019年 / 17卷 / 48期
基金：
中国国家自然科学基金;
关键词：
ASYMMETRIC TRANSFER HYDROGENATION; ALKYNES; REDUCTION; ALKENES; DEUTERIATION; HETEROCYCLES; QUINOLINES; CHEMISTRY; EFFICIENT; ESTER;
D O I：
10.1039/c9ob02095k
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Rhodium-catalyzed transfer hydrogenation of quinoxalines with water as a hydrogen source was reported. The reaction allowed the simple preparation of tetrahydroquinoxalines under mild conditions. The deuterium-labelling experiment confirmed that water is the sole hydrogen source in the transfer hydrogenation reaction.
引用
收藏
页码：10142 / 10147
页数：6
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