Highly efficient Zn2SnO4 perovskite solar cells through band alignment engineering

被引:19
作者
Dou, Jie [1 ,2 ]
Zhang, Ying [1 ,2 ]
Wang, Qiong [3 ]
Abate, Antonio [1 ,3 ]
Li, Yafeng [1 ,2 ]
Wei, Mingdeng [1 ,2 ,4 ]
机构
[1] Fuzhou Univ, Fujian Prov Key Lab Electrochem Energy Storage Ma, Fuzhou 350002, Fujian, Peoples R China
[2] Fuzhou Univ, State Key Lab Photo Catalysis Energy & Environm, Fuzhou 350002, Fujian, Peoples R China
[3] Helmholtz Zentrum Berlin Mat & Energie, Kekulestr 5, D-12489 Berlin 1, Germany
[4] Jiangsu Collaborat Innovat Ctr Photovolat Sci & E, Changzhou 213164, Peoples R China
基金
中国国家自然科学基金;
关键词
LIGHT-EMITTING-DIODES; LAYERS; IODIDE; ROUTE;
D O I
10.1039/c9cc07398a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
An active absorption layer with a narrow band gap has been achieved through adjusting the halide ratio in a halide perovskite, and it had better energy alignment with the Zn2SnO4 electron transport layer. An efficiency of 19.37% can be obtained, and this has also been improved to 20.26% through the incorporation of cesium, giving a new triple cation perovskite.
引用
收藏
页码:14673 / 14676
页数:4
相关论文
共 28 条
[11]   Perovskite light-emitting diodes with external quantum efficiency exceeding 20 per cent [J].
Lin, Kebin ;
Xing, Jun ;
Quan, Li Na ;
de Arquer, F. Pelayo Garcia ;
Gong, Xiwen ;
Lu, Jianxun ;
Xie, Liqiang ;
Zhao, Weijie ;
Zhang, Di ;
Yan, Chuanzhong ;
Li, Wenqiang ;
Liu, Xinyi ;
Lu, Yan ;
Kirman, Jeffrey ;
Sargent, Edward H. ;
Xiong, Qihua ;
Wei, Zhanhua .
NATURE, 2018, 562 (7726) :245-+
[12]   Mixed-Organic-Cation Perovskite Photovoltaics for Enhanced Solar-Light Harvesting [J].
Pellet, Norman ;
Gao, Peng ;
Gregori, Giuliano ;
Yang, Tae-Youl ;
Nazeeruddin, Mohammad K. ;
Maier, Joachim ;
Graetzel, Michael .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2014, 53 (12) :3151-3157
[13]   The Impact of Nano- and Microstructure on the Stability of Perovskite Solar Cells [J].
Phung, Nga ;
Abate, Antonio .
SMALL, 2018, 14 (46)
[14]   Improving the Extraction of Photogenerated Electrons with SnO2 Nanocolloids for Efficient Planar Perovskite Solar Cells [J].
Rao, Hua-Shang ;
Chen, Bai-Xue ;
Li, Wen-Guang ;
Xu, Yang-Fan ;
Chen, Hong-Yan ;
Kuang, Dai-Bin ;
Su, Cheng-Yong .
ADVANCED FUNCTIONAL MATERIALS, 2015, 25 (46) :7200-7207
[15]   How to Make over 20% Efficient Perovskite Solar Cells in Regular (n-i-p) and Inverted (p-i-n) Architectures [J].
Saliba, Michael ;
Correa-Baena, Juan-Pablo ;
Wolff, Christian M. ;
Stolterfoht, Martin ;
Phung, Nga ;
Albrecht, Steve ;
Neher, Dieter ;
Abate, Antonio .
CHEMISTRY OF MATERIALS, 2018, 30 (13) :4193-4201
[16]   Incorporation of rubidium cations into perovskite solar cells improves photovoltaic performance [J].
Saliba, Michael ;
Matsui, Taisuke ;
Domanski, Konrad ;
Seo, Ji-Youn ;
Ummadisingu, Amita ;
Zakeeruddin, Shaik M. ;
Correa-Baena, Juan-Pablo ;
Tress, Wolfgang R. ;
Abate, Antonio ;
Hagfeldt, Anders ;
Gratzel, Michael .
SCIENCE, 2016, 354 (6309) :206-209
[17]   Cesium-containing triple cation perovskite solar cells: improved stability, reproducibility and high efficiency [J].
Saliba, Michael ;
Matsui, Taisuke ;
Seo, Ji-Youn ;
Domanski, Konrad ;
Correa-Baena, Juan-Pablo ;
Nazeeruddin, Mohammad Khaja ;
Zakeeruddin, Shaik M. ;
Tress, Wolfgang ;
Abate, Antonio ;
Hagfeldt, Anders ;
Gratzel, Michael .
ENERGY & ENVIRONMENTAL SCIENCE, 2016, 9 (06) :1989-1997
[18]   Facile Deposition of Nb2O5 Thin Film as an Electron-Transporting Layer for Highly Efficient Perovskite Solar Cells [J].
Shen, Deli ;
Zhang, Weifeng ;
Li, Yafeng ;
Abate, Antonio ;
Wei, Mingdeng .
ACS APPLIED NANO MATERIALS, 2018, 1 (08) :4101-4109
[19]   Covering effect of conductive glass: a facile route to tailor the grain growth of hybrid perovskites for highly efficient solar cells [J].
Shen, Deli ;
Mao, Haijuan ;
Li, Yafeng ;
Abate, Antonio ;
Wei, Mingdeng .
JOURNAL OF MATERIALS CHEMISTRY A, 2018, 6 (41) :20289-20296
[20]   High-performance flexible perovskite solar cells exploiting Zn2SnO4 prepared in solution below 100 °C [J].
Shin, Seong Sik ;
Yang, Woon Seok ;
Noh, Jun Hong ;
Suk, Jae Ho ;
Jeon, Nam Joong ;
Park, Jong Hoon ;
Kim, Ju Seong ;
Seong, Won Mo ;
Seok, Sang Il .
NATURE COMMUNICATIONS, 2015, 6