Microwave-assisted, metal- and solvent-free synthesis of diaryl thioethers from aryl halides and carbon disulfide in the presence of [DBUH]+[OAc]-

被引：6

作者：

Zhou, Yongsheng ^{[1
]}

机构：

[1] Changzhou Univ, Sch Petrochem Engn, Changzhou 213164, Peoples R China

来源：

JOURNAL OF CHEMICAL RESEARCH | 2016年 / 05期

关键词：

diaryl thioethers; aryl halides; carbon disulfide; microwave-assisted; ionic liquids; diaryl sulfides; ONE-POT SYNTHESIS; CATALYZED S-ARYLATION; HIGHLY EFFICIENT; SULFIDES; THIOLS;

D O I：

10.3184/174751916X14605556925623

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A microwave-assisted direct coupling between aryl halides and carbon disulfide in ionic liquid [DBUH](+)[OAc](-)(DBU = 1,8-diazabicyclo-[5.4.0] undec-7-ene) has been developed. The reactions are very efficient, affording the corresponding diaryl thioethers in moderate to high yields. Aryl chlorides could also be reacted with carbon disulfide using this protocol. Moreover, [DBUH](+)[OAc](-) could be easily recovered and reused for several runs.

引用

页码：305 / 307

页数：3

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