Progress and Perspectives in Photo- and Electrochemical-Oxidation of Biomass for Sustainable Chemicals and Hydrogen Production

被引：331

作者：

Luo, Hui ^{[1
]}

Barrio, Jesus ^{[2
]}

Sunny, Nixon ^{[1
,3
]}

Li, Alain ^{[1
]}

Steier, Ludmilla ^{[2
]}

Shah, Nilay ^{[1
]}

Stephens, Ifan E. L. ^{[2
]}

Titirici, Maria-Magdalena ^{[1
]}

机构：

[1] Imperial Coll London, Dept Chem Engn, South Kensington Campus, London SW7 2AZ, England

[2] Imperial Coll London, Dept Mat, South Kensington Campus, London SW7 2AZ, England

[3] Imperial Coll London, Ctr Environm Policy, South Kensington Campus, London SW7 2AZ, England

来源：

ADVANCED ENERGY MATERIALS | 2021年 / 11卷 / 43期

基金：

英国工程与自然科学研究理事会;

关键词：

biomass; energy conversion; hydrogen production; life cycle analysis; photo/electrocatalysis; technoeconomical assessments; DENSITY-FUNCTIONAL THEORY; LAYERED DOUBLE HYDROXIDE; ALCOHOL FUEL-CELLS; ELECTROCATALYTIC GLYCEROL OXIDATION; PALLADIUM-BASED ELECTROCATALYSTS; ELECTRO-CATALYTIC OXIDATION; VISIBLE-LIGHT; ETHYLENE-GLYCOL; H-2; PRODUCTION; SELECTIVE OXIDATION;

D O I：

10.1002/aenm.202101180

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Biomass is recognized as an ideal CO2 neutral, abundant, and renewable resource substitute to fossil fuels. The rich proton content in most biomass derived materials, such as ethanol, 5-hydroxymethylfurfural (HMF) and glycerol allows it to be an effective hydrogen carrier. The oxidation derivatives, such as 2,5-difurandicarboxylic acid from HMF, glyceric acid from glycerol are valuable products to be used in biodegradable polymers and pharmaceuticals. Therefore, combining biomass-derived compound oxidation at the anode and hydrogen evolution reaction at the cathode in a biomass electrolysis or photo-reforming reactor would present a promising strategy for coproducing high value chemicals and hydrogen with low energy consumption and CO2 emissions. This review aims to combine fundamental knowledge on photo and electro-assisted catalysis to provide a comprehensive understanding of the general reaction mechanisms of different biomass-derived molecule oxidation. At the same time, catalyst requirements and recent advances for various feedstock compounds are also reviewed in detail. Technoeconomic assessment and life cycle analysis are performed on various feedstocks to assess the relative benefits of various processes, and finally critical prospects are given on the challenges and opportunities for technology development to meet the sustainability requirement of the future global energy economy.

引用

页数：51

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