ZrIV Coordination Polymers Based on a Naturally Occurring Phenolic Derivative

被引：37

作者：

Cooper, Lucy ^{[1
]}

Guillou, Nathalie ^{[1
]}

Martineau, Charlotte ^{[1
]}

Elkaim, Erik ^{[2
]}

Taulelle, Francis ^{[1
]}

Serre, Christian ^{[1
]}

Devic, Thomas ^{[1
]}

机构：

[1] Univ Versailles St Quentin Yvelines, CNRS, Inst Lavoisier Versailles, UMR 8180, F-78035 Versailles, France

[2] Synchrotron Soleil, Beamline Cristal Orme Merisiers, F-91192 Gif Sur Yvette, France

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2014年 / 36期

关键词：

Microporous materials; Metal-organic frameworks; Polymers; Structure elucidation; Zirconium; METAL-ORGANIC FRAMEWORKS; SODIUM PERCHLORATE MEDIUM; CATECHOL DERIVATIVES; ZIRCONIUM COMPLEXES; CRYSTAL-STRUCTURE; MODULATED SYNTHESIS; AQUEOUS-SOLUTION; STABILITY; UIO-66; 3,4,5-TRIHYDROXYBENZOATE;

D O I：

10.1002/ejic.201402891

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactivity under solvothermal conditions of the Zr-IV ion with the naturally occurring gallic acid ligand has been evaluated in depth. The study led to the isolation of four microcrystalline hydroxycarboxylate-based coordination polymers (MIL-151 to -154). Through the use of a combination of solid-state NMR and high-resolution X-ray powder diffraction analyses, the structures of two of these phases (MIL-153, MIL-154) were solved. In both cases, the gallol motifs favour the formation of rod-like inorganic units built up from ZrO8 polyhedra. Although one compound (MIL-151) was found to be microporous (S-BET approximate to 470 m(2)g(-1)), its poor crystallinity prevented comprehensive structural analysis. Nevertheless, a comparison of its physicochemical features with those of the fully characterized solids allows a plausible structural model to be proposed.

引用

页码：6281 / 6289

页数：9

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