ZrIV Coordination Polymers Based on a Naturally Occurring Phenolic Derivative

被引：35

作者：

Cooper, Lucy ^{[1
]}

Guillou, Nathalie ^{[1
]}

Martineau, Charlotte ^{[1
]}

Elkaim, Erik ^{[2
]}

Taulelle, Francis ^{[1
]}

Serre, Christian ^{[1
]}

Devic, Thomas ^{[1
]}

机构：

[1] Univ Versailles St Quentin Yvelines, CNRS, Inst Lavoisier Versailles, UMR 8180, F-78035 Versailles, France

[2] Synchrotron Soleil, Beamline Cristal Orme Merisiers, F-91192 Gif Sur Yvette, France

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2014年 / 36期

关键词：

Microporous materials; Metal-organic frameworks; Polymers; Structure elucidation; Zirconium; METAL-ORGANIC FRAMEWORKS; SODIUM PERCHLORATE MEDIUM; CATECHOL DERIVATIVES; ZIRCONIUM COMPLEXES; CRYSTAL-STRUCTURE; MODULATED SYNTHESIS; AQUEOUS-SOLUTION; STABILITY; UIO-66; 3,4,5-TRIHYDROXYBENZOATE;

D O I：

10.1002/ejic.201402891

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactivity under solvothermal conditions of the Zr-IV ion with the naturally occurring gallic acid ligand has been evaluated in depth. The study led to the isolation of four microcrystalline hydroxycarboxylate-based coordination polymers (MIL-151 to -154). Through the use of a combination of solid-state NMR and high-resolution X-ray powder diffraction analyses, the structures of two of these phases (MIL-153, MIL-154) were solved. In both cases, the gallol motifs favour the formation of rod-like inorganic units built up from ZrO8 polyhedra. Although one compound (MIL-151) was found to be microporous (S-BET approximate to 470 m(2)g(-1)), its poor crystallinity prevented comprehensive structural analysis. Nevertheless, a comparison of its physicochemical features with those of the fully characterized solids allows a plausible structural model to be proposed.

引用

页码：6281 / 6289

页数：9

共 62 条

[1] EXPO:: a program for full powder pattern decomposition and crystal structure solution [J].

Altomare, A ;

Burla, MC ;

Camalli, M ;

Carrozzini, B ;

Cascarano, GL ;

Giacovazzo, C ;

Guagliardi, A ;

Moliterni, AGG ;

Polidori, G ;

Rizzi, R .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1999, 32 :339-340

[2] Synthesis, Structure, Assembly, and Modulation of the CO2 Adsorption Properties of a Zinc-Adeninate Macrocycle [J].

An, Jihyun ;

Fiorella, Richard P. ;

Geib, Steven J. ;

Rosi, Nathaniel L. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (24) :8401-+

[3]

[Anonymous], 2009, Chem. Soc. Rev., V38

[4]

[Anonymous], 2012, CHEM REV, V112, P673

[5] CRYSTAL-STRUCTURE OF ANTIMONY-(III) PYROGALLATE, SB(C-6H-3O-3) H-20 [J].

AURIVILLIUS, B ;

SARNSTRAND, C .

ACTA CHEMICA SCANDINAVICA SERIES A-PHYSICAL AND INORGANIC CHEMISTRY, 1976, 30 (03) :232-234

[6] Oxygen sensing via phosphorescence quenching of doped metal-organic frameworks [J].

Barrett, Seth M. ;

Wang, Cheng ;

Lin, Wenbin .

JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (20) :10329-10334

[7] Tailoring of network dimensionality and porosity adjustment in Zr- and Hf-based MOFs [J].

Bon, Volodymyr ;

Senkovska, Irena ;

Weiss, Manfred S. ;

Kaskel, Stefan .

CRYSTENGCOMM, 2013, 15 (45) :9572-9577

[8] Zr- and Hf-Based Metal-Organic Frameworks: Tracking Down the Polymorphism [J].

Bon, Volodymyr ;

Senkovska, Irena ;

Baburin, Igor A. ;

Kaskel, Stefan .

CRYSTAL GROWTH & DESIGN, 2013, 13 (03) :1231-1237

[9] Zr(IV) and Hf(IV) based metal-organic frameworks with reo-topology [J].

Bon, Volodymyr ;

Senkovskyy, Volodymyr ;

Senkovska, Irena ;

Kaskel, Stefan .

CHEMICAL COMMUNICATIONS, 2012, 48 (67) :8407-8409

[10] Catechol derivatives of Group 4 and 5 compounds [J].

Boyle, TJ ;

Tribby, LJ ;

Alam, TM ;

Bunge, SD ;

Holland, GP .

POLYHEDRON, 2005, 24 (10) :1143-1152

← 1 2 3 4 5 6 7 →