Catalytic Hydrogen Evolution by Tungsten Disulfide at Liquid-Liquid Interfaces

被引:27
作者
Aslan, Emre [1 ]
Patir, Imren Hatay [1 ]
Ersoz, Mustafa [1 ]
机构
[1] Selcuk Univ, Dept Chem, TR-42031 Konya, Turkey
关键词
electrochemistry; electron transfer; hydrogen; interfaces; tungsten; TRANSITION-METAL DICHALCOGENIDES; WS2; DECAMETHYLFERROCENE; NANOCLUSTERS; MORPHOLOGY; NANOSHEETS; REDUCTION; EFFICIENT;
D O I
10.1002/cctc.201402473
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
WS2, which is composed of cheap and earth-abundant elements, catalyzes the hydrogen-evolution reaction efficiently using the organic electron-donor decamethylferrocene. This catalytic activity has been investigated at liquid-liquid interfaces (water-1,2-dichloroethane) by voltammetry and biphasic reactions observed by UV/Vis spectroscopy and GC.
引用
收藏
页码:2832 / 2835
页数:4
相关论文
共 24 条
[1]   Floating conductive catalytic nano-rafts at soft interfaces for hydrogen evolution [J].
Bian, Xiaojun ;
Scanlon, Micheal D. ;
Wang, Sinong ;
Liao, Lei ;
Tang, Yi ;
Liu, Baohong ;
Girault, Hubert H. .
CHEMICAL SCIENCE, 2013, 4 (09) :3432-3441
[2]   Hydrogen evolution on nano-particulate transition metal sulfides [J].
Bonde, Jacob ;
Moses, Poul G. ;
Jaramillo, Thomas F. ;
Norskov, Jens K. ;
Chorkendorff, Ib .
FARADAY DISCUSSIONS, 2008, 140 :219-231
[3]   The morphology of MoS2, WS2, Co-Mo-S, Ni-Mo-S and Ni-W-S nanoclusters in hydrodesulfurization catalysts revealed [J].
Brorson, M. ;
Carlsson, A. ;
Topsoe, H. .
CATALYSIS TODAY, 2007, 123 (1-4) :31-36
[4]   Morphology of WS2 nanoclusters in WS2/C hydrodesulfurization catalysts revealed by high-angle annular dark-field scanning transmission electron microscopy (HAADF-STEM) imaging [J].
Carlsson, A ;
Brorson, M ;
Topsoe, H .
JOURNAL OF CATALYSIS, 2004, 227 (02) :530-536
[5]   Photoinduced Biphasic Hydrogen Evolution: Decamethylosmocene as a Light-Driven Electron Donor [J].
Ge, Peiyu ;
Olaya, Astrid J. ;
Scanlon, Micheal D. ;
Patir, Imren Hatay ;
Vrubel, Heron ;
Girault, Hubert H. .
CHEMPHYSCHEM, 2013, 14 (10) :2308-2316
[6]   Biphasic water splitting by osmocene [J].
Ge, Peiyu ;
Todorova, Tanya K. ;
Patir, Imren Hatay ;
Olaya, Astrid J. ;
Vrubel, Heron ;
Mendez, Manuel ;
Hu, Xile ;
Corminboeuf, Clemence ;
Girault, Hubert H. .
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2012, 109 (29) :11558-11563
[7]  
Hatay I., 2009, ANGEW CHEM, V121, P5241
[8]   Hydrogen evolution at polarised liquid/liquid interfaces catalyzed by molybdenum disulfide [J].
Hatay, Imren ;
Ge, Pei Yu ;
Vrubel, Heron ;
Hu, Xile ;
Girault, Hubert H. .
ENERGY & ENVIRONMENTAL SCIENCE, 2011, 4 (10) :4246-4251
[9]   Hydrogen Evolution at Liquid-Liquid Interfaces [J].
Hatay, Imren ;
Siu, Bin ;
Li, Fei ;
Partovi-Nia, Raheleh ;
Vrubel, Heron ;
Hu, Xile ;
Ersoz, Mustafa ;
Girault, Hubert H. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (28) :5139-5142
[10]   Enhanced Electrocatalytic Properties of Transition-Metal Dichalcogenides Sheets by Spontaneous Gold Nanoparticle Decoration [J].
Kim, Jaemyung ;
Byun, Segi ;
Smith, Alexander J. ;
Yu, Jin ;
Huang, Jiaxing .
JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2013, 4 (08) :1227-1232