Crystal structure of a new organic condensed phosphate (C6H9N3O)H2P2O7

被引：10

作者：

Jouini, Noura ^{[1
]}

BenHamada, Latifa ^{[1
]}

Jouini, Amor ^{[1
]}

机构：

[1] Univ Ctr, Fac Sci Monastir, Dept Chim, Chim Solide Lab, Monastir 5019, Tunisia

来源：

MATERIALS RESEARCH BULLETIN | 2007年 / 42卷 / 01期

关键词：

chemical synthesis; infrared spectroscopy; X-ray diffraction; crystal structure;

D O I：

10.1016/j.materresbull.2006.05.018

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Crystals of a new organic compound, the isonicotinic acid hydrazide dihydrogendiphosphate, (C6H9N3O)H2P2O7 (denoted INHDP) were prepared and grown at room temperature. The INHDP crystallizes in the triclinic system with the P (1) over bar space group. Its unit cell dimensions are: a = 7.316(3) angstrom, b = 7.783(3) angstrom, c = 10.802(4) angstrom, alpha = 82.41(3)degrees, beta = 75.19(3)degrees, gamma = 72.57(3)degrees, with V = 566.3(4) angstrom(3) and Z = 2. Crystal structure has been determined and refined to a reliability R factor of 0.0389. The atomic arrangement can be described as inorganic infinite ribbons of H2P2O72- anions spreading parallel to the b-axis. These ribbons are themselves interconnected by the organic (C6H9N3O)(+) cations so as to build a three dimensional arrangement. In the present work, we describe the crystal structure, thermal behaviour and IR analysis of this new compound. (C) 2006 Elsevier Ltd. All rights reserved.

引用

页码：56 / 63

页数：8

共 21 条

[1] Synthesis, crystal structure, and characterization of a new diphosphate, (m-CH3C6H4NH3)2H2P2O7 [J].

Akriche, S ;

Rzaigui, M .

MATERIALS RESEARCH BULLETIN, 2000, 35 (14-15) :2545-2553

[2] Crystal growth and structure of (2-C2H5C6H4NH3)2H2P2O7 [J].

Akriche, S ;

Rzaigui, M .

MATERIALS RESEARCH BULLETIN, 2001, 36 (1-2) :375-382

[3]

AVERBUCHPOUCHOT MT, 1993, CR ACAD SCI II, V316, P187

[4]

AVERBUCHPOUCHOT MT, 1992, EUR J SOL STATE INOR, V29, P411

[5]

AVERBUCHPOUCHOT MT, 1993, CR ACAD SCI II, V316, P41

[6] STRUCTURE OF PUTRESCINIUM DIHYDROGENDIPHOSPHATE [J].

BARTOSZAK, E ;

JASKOLSKI, M .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1990, 46 :2158-2160

[7] GEOMETRY OF POLYHEDRAL DISTORTIONS - PREDICTIVE RELATIONSHIPS FOR PHOSPHATE GROUP [J].

BAUR, WH .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1974, 30 (MAY15) :1195-1215

[8] Crystal structure of a new organic dihydrogenomonophosphate (C6H8N3O)2(H2PO4)2 [J].

BenHamada, L. ;

Jouini, A. .

MATERIALS RESEARCH BULLETIN, 2006, 41 (10) :1917-1924

[9] GEOMETRY OF O-H...O HYDROGEN-BONDS [J].

BROWN, ID .

ACTA CRYSTALLOGRAPHICA SECTION A, 1976, 32 (JAN1) :24-31

[10] SOLID-STATE VIBRATIONAL-SPECTRA OF CALCIUM PYROPHOSPHATE DIHYDRATE [J].

CORNILSEN, BC .

JOURNAL OF MOLECULAR STRUCTURE, 1984, 117 (1-2) :1-9

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