Synthesis, structure and dehydrogenation of magnesium amidoborane monoammoniate

被引：58

作者：

Chua, Yong Shen ^{[2
]}

Wu, Guotao ^{[1
]}

Xiong, Zhitao ^{[1
]}

Karkamkar, Abhi ^{[3
]}

Guo, Jianping ^{[1
]}

Jian, Mingxian ^{[2
]}

Wong, Ming Wah ^{[2
]}

Autrey, Thomas ^{[3
]}

Chen, Ping ^{[1
]}

机构：

[1] Dalian Inst Chem Phys, Dalian 116023, Peoples R China

[2] Natl Univ Singapore, Dept Chem, Singapore 117542, Singapore

[3] Pacific NW Natl Lab, Richland, WA 99352 USA

来源：

CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 31期

关键词：

HYDROGEN STORAGE; LITHIUM BOROHYDRIDE; AMMONIA-BORANE;

D O I：

10.1039/c0cc01260b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Magnesium amidoborane monoammoniate (Mg(NH2BH3)(2)center dot NH3) which crystallizes in a monoclinic structure (space group P2(1)/a) has been synthesized by reacting MgNH with NH3BH3. Dihydrogen bonds are established between coordinated NH3 and BH3 of [NH2BH3](-) in the structure, promoting stoichiometric conversion of NH3 to H-2.

引用

页码：5752 / 5754

页数：3

共 15 条

[1] Interaction of hydrogen with metal nitrides and imides [J].

Chen, P ;

Xiong, ZT ;

Luo, JZ ;

Lin, JY ;

Tan, KL .

NATURE, 2002, 420 (6913) :302-304

[2] Calcium Amidoborane Ammoniate-Synthesis, Structure, and Hydrogen Storage Properties [J].

Chua, Yong Shen ;

Wu, Guotao ;

Xiong, Zhitao ;

He, Teng ;

Chen, Ping .

CHEMISTRY OF MATERIALS, 2009, 21 (20) :4899-4904

[3] Calcium amidotrihydroborate: A hydrogen storage material [J].

Diyabalanage, Himashime V. K. ;

Shrestha, Roshan P. ;

Semelsberger, Troy A. ;

Scott, Brian L. ;

Bowden, Mark E. ;

Davis, Benjamin L. ;

Burrell, Anthony K. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (47) :8995-8997

[4] THE CRYSTAL STRUCTURE OF AMMONIA-BORANE, H3NBH3 [J].

HUGHES, EW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1956, 78 (02) :502-503

[5] The Monoammoniate of Lithium Borohydride, Li(NH3)BH4: An Effective Ammonia Storage Compound [J].

Johnson, Simon R. ;

David, William I. F. ;

Royse, David M. ;

Sommariva, Marco ;

Tang, Christina Y. ;

Fabbiani, Francesca P. A. ;

Jones, Martin O. ;

Edwards, Peter P. .

CHEMISTRY-AN ASIAN JOURNAL, 2009, 4 (06) :849-854

[6] Ammonia borane destabilized by lithium hydride: An advanced on-board hydrogen storage material [J].

Kang, Xiangdong ;

Fang, Zhanzhao ;

Kong, Lingyan ;

Cheng, Huiming ;

Yao, Xiangdong ;

Lu, Gaoqing ;

Wang, Ping .

ADVANCED MATERIALS, 2008, 20 (14) :2756-+

[7] Structural and energetic analysis of the hydrogen storage materials LiNH2BH3 and NaNH2BH3 from ab initio calculations [J].

Ramzan, M. ;

Silvearv, F. ;

Blomqvist, A. ;

Scheicher, R. H. ;

Lebegue, S. ;

Ahuja, R. .

PHYSICAL REVIEW B, 2009, 79 (13)

[8] Ammine magnesium borohydride complex as a new material for hydrogen storage:: Structure and properties of Mg(BH4)2•2NH3 [J].

Soloveichik, Grigorii ;

Her, Jae Hyuk ;

Stephens, Peter W. ;

Gao, Yan ;

Rijssenbeek, Job ;

Andrus, Matt ;

Zhao, J. -C. .

INORGANIC CHEMISTRY, 2008, 47 (10) :4290-4298

[9] Indirect, reversible high-density hydrogen storage in compact metal ammine salts [J].

Sorensen, Rasmus Z. ;

Hummelshoj, Jens S. ;

Klerke, Asbjorn ;

Reves, Jacob Birke ;

Vegge, Tejs ;

Norskov, Jens K. ;

Christensen, Claus H. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (27) :8660-8668

[10] Synthesis and structure of a magnesium-amidoborane complex and its role in catalytic formation of a new bis-aminoborane ligand [J].

Spielmann, Jan ;

Bolte, Michael ;

Harder, Sjoerd .

CHEMICAL COMMUNICATIONS, 2009, (45) :6934-6936

← 1 2 →