Synthesis and Crystal Structure of a New Three-Dimensional Complex Constructed From Thiophene-2,5-Dicarboxylic Acid

被引:10
作者
Zhao, Yan [1 ]
Li, Shi-Hui [2 ]
机构
[1] Luoyang Normal Univ, Coll Phys & Elect Informat, Luoyang 471022, Peoples R China
[2] Luoyang Normal Univ, Coll Chem & Chem Engn, Luoyang 471022, Peoples R China
关键词
thiophene-2; 5-dicarboxylic acid; hydrothermal synthesis; crystal structure; METAL-ORGANIC FRAMEWORK; COORDINATION POLYMERS; MAGNETIC-PROPERTIES; LUMINESCENT;
D O I
10.1080/15533174.2013.843565
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A new three-dimensional (3D) coordination polymer has been synthesized under hydrothermal conditions and characterized by elemental analysis, IR spectroscopy, and X-ray diffraction. The X-ray diffraction analysis reveals that the polymer crystallizes in monoclinic system, space group C2/c. Unit cell parameters: a = 25.444(2), b = 5.8508(5), c = 19.0633(17) angstrom, = 90 degrees, = 124.1250(10)degrees, = 90 degrees, V = 2349.2(4) angstrom(3), Z = 4. The polymer can be specified by the Schlafli symbol (4(2)6(4))(4(2)6(7)8) as a 3D (4,5)-connected net.
引用
收藏
页码:921 / 925
页数:5
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