Reaction of the [B10H9O2C4H8]- anion with C-nucleophiles

被引：9

作者：

Matveev, E. Yu ^{[1
,2
]}

Akimov, S. S. ^{[3
]}

Kubasov, A. S. ^{[1
]}

Nichugovskii, A. I. ^{[2
]}

Nartov, A. S. ^{[4
]}

Retivov, V. M. ^{[4
]}

Zhizhina, K. Yu ^{[1
,2
]}

Kuznetsov, N. T. ^{[1
]}

机构：

[1] Russian Acad Sci, Kurnakov Inst Gen & Inorgan Chem, Moscow 117907, Russia

[2] Moscow Technol Univ MITHT, Moscow 119571, Russia

[3] Chimmed Ltd, Moscow 115230, Russia

[4] Fed State Unitary Enterprise Res Inst Chem Reagen, Moscow 107076, Russia

来源：

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2017年 / 62卷 / 06期

基金：

俄罗斯基础研究基金会;

关键词：

CLOSO-DODECABORATE ANION; OXONIUM DERIVATIVES; IRON(II) CLATHROCHELATE; DECABORATE ANION; SUBSTITUENTS; CLEAVAGE;

D O I：

10.1134/S0036023617060146

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactions of 1,4-dioxane-substituted closo-decaborate anion ([B10H9O2C4H8](-)) with metal acetylenides, diethyl malonate, ethyl acetoacetate, triethyl orthoformate, acetylacetone, and malonodinitrile were studied. The reactions were shown to be accompanied with substituent ring opening and attachment of the corresponding pendant functional group. The obtained compounds were characterized by various physicochemical methods (IR and polynuclear NMR spectroscopy, ESI mass spectrometry).

引用

页码：808 / 813

页数：6

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