Reaction of the [B10H9O2C4H8]- anion with C-nucleophiles

被引：9

作者：

Matveev, E. Yu ^{[1
,2
]}

Akimov, S. S. ^{[3
]}

Kubasov, A. S. ^{[1
]}

Nichugovskii, A. I. ^{[2
]}

Nartov, A. S. ^{[4
]}

Retivov, V. M. ^{[4
]}

Zhizhina, K. Yu ^{[1
,2
]}

Kuznetsov, N. T. ^{[1
]}

机构：

[1] Russian Acad Sci, Kurnakov Inst Gen & Inorgan Chem, Moscow 117907, Russia

[2] Moscow Technol Univ MITHT, Moscow 119571, Russia

[3] Chimmed Ltd, Moscow 115230, Russia

[4] Fed State Unitary Enterprise Res Inst Chem Reagen, Moscow 107076, Russia

来源：

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2017年 / 62卷 / 06期

基金：

俄罗斯基础研究基金会;

关键词：

CLOSO-DODECABORATE ANION; OXONIUM DERIVATIVES; IRON(II) CLATHROCHELATE; DECABORATE ANION; SUBSTITUENTS; CLEAVAGE;

D O I：

10.1134/S0036023617060146

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactions of 1,4-dioxane-substituted closo-decaborate anion ([B10H9O2C4H8](-)) with metal acetylenides, diethyl malonate, ethyl acetoacetate, triethyl orthoformate, acetylacetone, and malonodinitrile were studied. The reactions were shown to be accompanied with substituent ring opening and attachment of the corresponding pendant functional group. The obtained compounds were characterized by various physicochemical methods (IR and polynuclear NMR spectroscopy, ESI mass spectrometry).

引用

页码：808 / 813

页数：6

共 13 条

[1] Conjugates of boron clusters with derivatives of natural chlorin and bacteriochlorin [J].

Bregadze, V. I. ;

Sivaev, I. B. ;

Lobanova, I. A. ;

Titeev, R. A. ;

Brittal, D. I. ;

Grin, M. A. ;

Mironov, A. F. .

APPLIED RADIATION AND ISOTOPES, 2009, 67 (7-8) :S101-S104

[2] Synthesis of a cycloimide bacteriochlorin p conjugate with the closo-dodecaborate anion [J].

Grin, Mikhail A. ;

Semioshkin, Andrey A. ;

Titeev, Rustam A. ;

Nizhnik, Evgeniya A. ;

Grebenyuk, Julia N. ;

Mironov, Andrey F. ;

Bregadze, Vladimir I. .

MENDELEEV COMMUNICATIONS, 2007, 17 (01) :14-15

[3]

Ingold C., 1969, Structure and Mechanism in Organic Chemistry

[4] First example of the ribbed-functionalized iron(ii) clathrochelate with six pendante closo-borate substituents [J].

Kuznetsov, N. T. ;

Belaya , I. G. ;

Dolganov, A. V. ;

Zelinskii, G. E. ;

Matveev, E. Yu. ;

Zhizhin, K. Yu. ;

Voloshin, Ya. Z. ;

Bubnov, Yu. N. .

RUSSIAN CHEMICAL BULLETIN, 2011, 60 (12) :2518-2521

[5] Cleavage of the cyclic substituent in the [B10H9O2C4H8]-, [B10H9OC4H8]-, and [B10H9OC5H10]- anions upon the interaction with negatively charged N-nucleophiles [J].

Matveev, E. Yu. ;

Retivov, V. M. ;

Razgonyaeva, G. A. ;

Zhizhin, K. Yu. ;

Kuznetsov, N. T. .

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2011, 56 (10) :1549-1554

[6] Oxonium derivatives of closo-decaborate in reactions with sulfur-containing nucleophiles [J].

Matveev, E. Yu ;

Razgonyaeva, G. A. ;

Mustyatsa, V. N. ;

Votinova, N. A. ;

Zhizhin, K. Yu ;

Kuznetsov, N. T. .

RUSSIAN CHEMICAL BULLETIN, 2010, 59 (03) :556-559

[7] Synthesis of novel derivatives of closo-dodecaborate anion with azido group at the terminal position of the spacer [J].

Orlova, Anna V. ;

Kondakov, Nikolay N. ;

Kimel, Boris G. ;

Kononov, Leonid O. ;

Kononova, Elena G. ;

Sivaev, Igor B. ;

Bregadze, Vladimir I. .

APPLIED ORGANOMETALLIC CHEMISTRY, 2007, 21 (02) :98-100

[8] Ring opening of tetrahydropyran attached to undecahydro-closo-dodecaborate(1-) by nucleophiles [J].

Peymann, T ;

Kuck, K ;

Gabel, D .

INORGANIC CHEMISTRY, 1997, 36 (22) :5138-5139

[9] Synthesis of carboxylic acids based on the closo-decaborate anion [J].

Prikaznov, Alexander V. ;

Shmal'ko, Akim V. ;

Sivaev, Igor B. ;

Petrovskii, Pavel V. ;

Bragin, Vikentii I. ;

Kisin, Alexander V. ;

Bregadze, Vladimir V. .

POLYHEDRON, 2011, 30 (09) :1494-1501

[10] Cyclic oxonium derivatives of polyhedral boron hydrides and their synthetic applications [J].

Semioshkin, Andrey A. ;

Sivaev, Igor B. ;

Bregadze, Vladimir I. .

DALTON TRANSACTIONS, 2008, 8 (08) :977-992

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