Transition metal thiolato complexes as synthons - II. Syntheses and structural characteristics of bidentate phosphine and bidentate thiolato complexes of cobalt and nickel

被引：0
|
作者：
Kang, BS [1 ]
Chen, ZN
Gao, HR
Zhou, ZY
Wu, BM
Mak, TMC
Lin, Z
机构：
[1] Zhongshan Univ, Dept Chem, Guangzhou 510275, Peoples R China
[2] Chinese Univ Hong Kong, Dept Chem, Sha Tin 100083, NT, Hong Kong
[3] Chinese Acad Sci, Fujian Inst Res Struct Matter, Fuzhou 350002, Peoples R China
[4] Chinese Acad Sci, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China
来源：
ACTA CHIMICA SINICA | 1998年 / 56卷 / 01期
关键词：
stuctural units; mixed phosphine-thiolato complex; phosphine-thiolato cobalt complex; phosphine-thiolato nickel complex; crystal structure; structural regularities;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Mononuclear complexes Co(bdt)(dppe)(1), Ni(tdt)(dppm)(2), and Ni(tsal)(dppe) (3)containingboth bidentate phosphine (PP) and bidentate thiolato (SX, X = S,O) ligands were synthesized and structurally characterized. The metal centers are all square planar in geometry composed of SXP2 from the two ligands forming four-, five-, or six-membered chelate rings. Structural characteristics of the complexes are summarized and the resistance of these complexes to the construction into polynuclear cluster compounds is discussed.
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页码：58 / 67
页数：10
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