Silver(I) Coordination Polymer Based on a Schiff Base Ligand: Synthesis, Crystal Structure and Luminescent Properties

被引：13
作者：
Dang, Dong-Bin [1 ]
Zheng, Guang-Shui [1 ]
Bai, Yan [1 ]
机构：
[1] Henan Univ, Sch Chem & Chem Engn, Inst Mol & Crystal Engn, Kaifeng 475004, Peoples R China
来源：
JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS | 2010年 / 20卷 / 02期
基金：
中国国家自然科学基金; 中国博士后科学基金;
关键词：
Silver(I); Coordination polymer; Schiff base; Crystal structure; Luminescence; MAGNETIC-PROPERTIES; COMPLEXES; ARCHITECTURES; COMPOUND; SERIES; BRIDGE;
D O I：
10.1007/s10904-010-9349-6
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
A new Ag(I) coordination polymer [AgL(NO3)] (n) 1 (L = 4-benzoylpyridine hydrazone) has been synthesized and characterized by IR, UV, elemental analysis, thermogravimetry and X-ray crystallography. Ag(I)-atom has a seesaw environment with a set of donors from three N-atoms of three ligands and one O-atom from one NO3 (-) anion. Each ligand is bonded to three silver centers and each silver atom is coordinated by three ligands thereby generating two types of bimetallic metallocyclic unit to form a 1D chain. The 1D chains interact each other giving further rise to a 3D supramolecular network through multiform intermolecular hydrogen bonds. The luminescent properties of the polymer 1 at room temperature were investigated.
引用
收藏
页码：356 / 360
页数：5
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