Silver(I) Coordination Polymer Based on a Schiff Base Ligand: Synthesis, Crystal Structure and Luminescent Properties

被引：13

作者：

Dang, Dong-Bin ^{[1
]}

Zheng, Guang-Shui ^{[1
]}

Bai, Yan ^{[1
]}

机构：

[1] Henan Univ, Sch Chem & Chem Engn, Inst Mol & Crystal Engn, Kaifeng 475004, Peoples R China

来源：

JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS | 2010年 / 20卷 / 02期

基金：

中国国家自然科学基金; 中国博士后科学基金;

关键词：

Silver(I); Coordination polymer; Schiff base; Crystal structure; Luminescence; MAGNETIC-PROPERTIES; COMPLEXES; ARCHITECTURES; COMPOUND; SERIES; BRIDGE;

D O I：

10.1007/s10904-010-9349-6

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A new Ag(I) coordination polymer [AgL(NO3)] (n) 1 (L = 4-benzoylpyridine hydrazone) has been synthesized and characterized by IR, UV, elemental analysis, thermogravimetry and X-ray crystallography. Ag(I)-atom has a seesaw environment with a set of donors from three N-atoms of three ligands and one O-atom from one NO3 (-) anion. Each ligand is bonded to three silver centers and each silver atom is coordinated by three ligands thereby generating two types of bimetallic metallocyclic unit to form a 1D chain. The 1D chains interact each other giving further rise to a 3D supramolecular network through multiform intermolecular hydrogen bonds. The luminescent properties of the polymer 1 at room temperature were investigated.

引用

页码：356 / 360

页数：5

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