In situ characterisation of mechanically-induced self-propagating reactions

被引:35
作者
Deidda, C
Delogu, F
Cocco, G
机构
[1] Univ Sassari, Dipartimento Chim, I-07100 Sassari, Italy
[2] Univ Cagliari, Dipartimento Ingn Chim & Mat, I-09123 Cagliari, Italy
关键词
Polymer; Combustion; Quartz; Carbide; Milling;
D O I
10.1023/B:JMSC.0000039236.48464.8f
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Transparent quartz vials were employed for a direct viewing of ignition and propagation phenomena in combustion-like reactions under milling. Combustion temperatures were measured from infrared light emission by two-colours pyrometers. Such a methodological approach allowed one the in situ characterisation of the self-propagating behaviour of a variety of carbides and silicides. Experimental combustion temperatures close to the theoretically calculated adiabatic ones were observed for the reaction which goes to completion within millisecond period. (C) 2004 Kluwer Academic Publishers.
引用
收藏
页码:5315 / 5318
页数:4
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