Chemical modification of Tilapia oil for biolubricant applications

被引：84

作者：

do Valle, Camila Peixoto ^{[1
]}

Rodrigues, Jailson Silva ^{[1
]}

Uchoa Dutra Fechine, Lillian Maria ^{[1
]}

Cunha, Arcelina Pacheco ^{[1
]}

Malveira, Jackson Queiroz ^{[2
]}

Tavares Luna, Francisco Murilo ^{[3
]}

Pontes Silva Ricardo, Nagila Maria ^{[1
]}

机构：

[1] Univ Fed Ceara, Dept Organ & Inorgan Chem, POB 6021, BR-60440900 Fortaleza, Ceara, Brazil

[2] Technol Ctr Fdn Ceara, Prof Romulo Proenca St,Campus Pici, BR-60455700 Fortaleza, Ceara, Brazil

[3] Univ Fed Ceara, Dept Chem Engn, Nucleo Pesquisas Lubrificantes, Bl 1010, BR-60455900 Fortaleza, Ceara, Brazil

来源：

JOURNAL OF CLEANER PRODUCTION | 2018年 / 191卷

关键词：

Biolubricants; Nile Tilapia oil; Epoxidation; Ring-opening reaction; Biodegradability; ACID METHYL-ESTERS; OLEIC-ACID; LOW-TEMPERATURE; CASTOR-OIL; BASE STOCK; EPOXIDATION; LUBRICANTS; STABILITY; WASTE; DERIVATIVES;

D O I：

10.1016/j.jclepro.2018.04.062

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

Nowadays, around 40% of the lubricant market is dominated by petroleum-derived products, resulting in a negative impact on environment. Herein, it was aimed to develop a biodegradable lubricant-grade ester using Tilapia oil as primary feedstock. The synthetic route was carried out in three steps: (1) transesterification, (2) epoxidation and (3) ring-opening reaction with different long chain alcohols, where the final esters were characterised regarding their physicochemical properties. The lubricant-grade esters showed superior biodegradability and viscosity index (>117) compared to commercial petroleum-based oils. The ester synthesized with 2-ethyl hexanol showed highest thermal stability (T-onset = 230 degrees C) compared to other long chain alcohols. Therefore, as mainly proposed, this study shows that esters from Tilapia oil have a great potential to obtain lubricants with high biodegradability and better physicochemical properties. (C) 2018 Elsevier Ltd. All rights reserved.

引用

页码：158 / 166

页数：9

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