Cp2TiCl: An Ideal Reagent for Green Chemistry?

被引：38

作者：

Castro Rodriguez, Maria ^{[1
]}

Rodriguez Garcia, Ignacio ^{[2
]}

Rodriguez Maecker, Roman Nicolay ^{[3
]}

Pozo Morales, Laura ^{[1
]}

Enrique Oltra, J. ^{[4
]}

Rosales Martinez, Antonio ^{[1
,3
,5
]}

机构：

[1] Univ Seville, Escuela Politecn Super, Dept Chem Engn, Seville 41011, Spain

[2] Univ Almeria, ceiA3, Organ Chem, Almeria 04120, Spain

[3] Univ Fuerzas Armadas ESPE, Petrochem Engn, Latacunga 050150, Ecuador

[4] Univ Granada, Fac Sci, Dept Organ Chem, E-18071 Granada, Spain

[5] Univ Seville, Escuela Politecn Super, Dept Chem & Environm Engn, Seville 41011, Spain

来源：

ORGANIC PROCESS RESEARCH & DEVELOPMENT | 2017年 / 21卷 / 07期

关键词：

FREE-RADICAL CHEMISTRY; CATALYZED REDUCTIVE UMPOLUNG; STRAIGHTFORWARD SYNTHESIS; TI-III; ELECTRON-TRANSFER; ENANTIOSELECTIVE SYNTHESIS; TITANOCENE CHLORIDE; SELECTIVE REDUCTION; TITANIUM COMPLEXES; ACTIVATED ALKENES;

D O I：

10.1021/acs.oprd.7b00098

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The development of Green Chemistry inevitably involves the development of green reagents. In this review, we highlight that Cp2TiCl is a reagent widely used in radical and organometallic chemistry, which shows, if not all, at least some of the 12 principles summarized for Green Chemistry, such as waste minimization, catalysis, safer solvents, toxicity, energy efficiency, and atom economy. Also, this complex has proved to be an ideal reagent for green C-C and C-O bond forming reactions, green reduction, isomerization, and deoxygenation reactions of several functional organic groups as we demonstrate throughout the review.

引用

页码：911 / 923

页数：13

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