Metal-bound chlorine often accepts hydrogen bonds

被引：543

作者：

Aullón, G

Bellamy, D

Brammer, L

Bruton, EA

Orpen, AG

机构：

[1] Univ Missouri, Dept Chem, St Louis, MO 63121 USA

[2] Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 06期

关键词：

D O I：

10.1039/a709014e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Analysis of 6624 crystallographically characterised hydrogen bonds containing M-Cl, C-Cl or Cl- and either HO or HN groups show that M-Cl moieties are good, anisotropic hydrogen-bond accepters forming hydrogen bonds similar in length to those of the chloride anion, while C-Cl moieties are very poor hydrogen-bond accepters.

引用

收藏

页码：653 / 654

页数：2

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