2-aminoethylammonium tris(1,2-ethylenediamine)nickel(II) tetraselenoantimonate(V)

被引：4

作者：

Fu, ML

Chen, WT

Cai, LZ

Zhou, GW

Guo, GC ^{[1
]}

Mao, JG

Huang, JS

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China

[2] Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2003年 / 59卷

关键词：

D O I：

10.1107/S1600536803009243

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The new molecular metal chalcogenide, (enH)[Ni(en)(3)][-SbSe4] or (C2H9N2)[Ni(C2H8N2)(3)][SbSe4], has been synthesized by a solvothermal reaction in an ethylenediamine/methanol solution at 443 K. The structure contains tetrahedral SbSe43-. anions and octahedral [Ni(en)(3)](2+) cations, as well as the monoprotonated ethylenediamine cation [enH](+).

引用

页码：M367 / M369

页数：3

共 12 条

[1] Solvothermal synthesis of [Mn(en)(3)](2)[Mn-4(en)(9)(SbSe4)(4)]center dot 2H2O: the first example of a selenoantimonate(v) acting as a ligand in a transition-metal complex [J].

Bensch, W ;

Nather, C ;

Schur, M .

CHEMICAL COMMUNICATIONS, 1997, (18) :1773-1774

[2] Novel sandwiched intermetallic selenoantimonates:: Soft synthesis and characterization of Cu2SbSe3•0.5en and Cu2SbSe3•en [J].

Chen, Z ;

Dilks, RE ;

Wang, RJ ;

Lu, JY ;

Li, J .

CHEMISTRY OF MATERIALS, 1998, 10 (10) :3184-3188

[3] Molecular building blocks for solid-state chalcogenides:: solvothermal synthesis of [Mn(en)3]Te4 and [Fe(en)3]2(Sb2Se5) [J].

Chen, Z ;

Wang, RJ ;

Huang, XY ;

Li, J .

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2000, 56 (09) :1100-1103

[4]

Girard MR, 1998, MAIN GROUP MET CHEM, V21, P231

[5] Synthesis and characterization of two group 15 selenometalates: [NEt(4)][BiSe2] and [Ge(en)(3)][enH][SbSe4] [J].

Pell, MA ;

Ibers, JA .

INORGANIC CHEMISTRY, 1996, 35 (16) :4559-4562

[6]

*RIG CORP, 2002, CRYST VERS 1 35

[7]

SAITO Y, 1979, INORGANIC MOL DISSYM, P56

[8] Chalcogenidometalates of the heavier Group 14 and 15 elements [J].

Sheldrick, WS ;

Wachhold, M .

COORDINATION CHEMISTRY REVIEWS, 1998, 176 :211-322

[9]

Sheldrick WS, 1997, ANGEW CHEM INT EDIT, V36, P207

[10] Synthesis and structure of Cs2Te13 and Cs4Te28, tellurium-rich tellurides on the methanolothermal route to Cs3Te22 [J].

Sheldrick, WS ;

Wachhold, M .

CHEMICAL COMMUNICATIONS, 1996, (05) :607-608

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