Palladacycles in catalysis - a critical survey

被引：484
作者：
Beletskaya, IP [1 ]
Cheprakov, AV [1 ]
机构：
[1] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119899, Russia
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2004年 / 689卷 / 24期
关键词：
palladium; palladacycle; catalysis; cross-coupling; pincer; Heck reaction;
D O I：
10.1016/j.jorganchem.2004.07.054
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The application of palladacycles as catalysts for cross-coupling and similar reactions is reviewed. In the majority of cases palladacycles are likely to serve as a source of highly active but unstable zero-valent palladium species. In this respect the palladacycles resemble the so-called phosphine-free catalysts. The advantages and limitations of palladacycle catalysts are discussed. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码：4055 / 4082
页数：28
相关论文
共 153 条
  • [1] Orthopalladated triarylphosphite complexes as highly efficient catalysts in the Heck reaction
    Albisson, DA
    Bedford, RB
    Scully, PN
    [J]. TETRAHEDRON LETTERS, 1998, 39 (52) : 9793 - 9796
  • [2] Orthopalladated triaryl phosphite complexes as highly active catalysts in biaryl coupling reactions
    Albisson, DA
    Bedford, RB
    Lawrence, SE
    Scully, PN
    [J]. CHEMICAL COMMUNICATIONS, 1998, (19) : 2095 - 2096
  • [3] Albrecht M, 2001, ANGEW CHEM INT EDIT, V40, P3750, DOI 10.1002/1521-3773(20011015)40:20<3750::AID-ANIE3750>3.0.CO
  • [4] 2-6
  • [5] Oxime palladacycles:: Stable and efficient catalysts for carbon-carbon coupling reactions
    Alonso, DA
    Nájera, C
    Pacheco, MC
    [J]. ORGANIC LETTERS, 2000, 2 (13) : 1823 - 1826
  • [6] Highly active oxime-derived palladacycle complexes for Suzuki-Miyaura and Ullmann-type coupling reactions
    Alonso, DA
    Nájera, C
    Pacheco, MC
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 2002, 67 (16) : 5588 - 5594
  • [7] Alonso DA, 2002, ADV SYNTH CATAL, V344, P172, DOI 10.1002/1615-4169(200202)344:2<172::AID-ADSC172>3.0.CO
  • [8] 2-9
  • [9] An N-heterocyclic carbene ligand with flexible steric bulk allows Suzuki cross-coupling of sterically hindered aryl chlorides at room temperature
    Altenhoff, G
    Goddard, R
    Lehmann, CW
    Glorius, F
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (31) : 3690 - 3693
  • [10] Mechanistic and kinetic studies of palladium catalytic systems
    Amatore, C
    Jutand, A
    [J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1999, 576 (1-2) : 254 - 278
12345678910