Palladacycles in catalysis - a critical survey

被引：483

作者：

Beletskaya, IP ^{[1
]}

Cheprakov, AV ^{[1
]}

机构：

[1] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119899, Russia

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2004年 / 689卷 / 24期

关键词：

palladium; palladacycle; catalysis; cross-coupling; pincer; Heck reaction;

D O I：

10.1016/j.jorganchem.2004.07.054

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The application of palladacycles as catalysts for cross-coupling and similar reactions is reviewed. In the majority of cases palladacycles are likely to serve as a source of highly active but unstable zero-valent palladium species. In this respect the palladacycles resemble the so-called phosphine-free catalysts. The advantages and limitations of palladacycle catalysts are discussed. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：4055 / 4082

页数：28

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